Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

H. Sohn; J. Camacho-Bunquin; R. R. Langeslay; P. A. Ignacio-De Leon; J. Niklas; O. G. Poluektov; C. Liu; J. G. Connell; D. Yang; J. Kropf; H. Kim; P. C. Stair; M. Ferrandon; M. Delferro

doi:10.1039/c7cc01876b

Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

H. Sohn, J. Camacho-Bunquin, R. R. Langeslay, P. A. Ignacio-De Leon, J. Niklas, O. G. Poluektov, C. Liu, J. G. Connell, D. Yang, J. Kropf, H. Kim, P. C. Stair, M. Ferrandon, M. Delferro

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26 Scopus citations

Abstract

A well-defined, isolated, single-site organovanadium(iii) catalyst on SiO₂ [(SiO₂)V(Mes)(THF)] was synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, ¹H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalyst exhibits unprecedented reactivity in liquid-and gas-phase alkene/alkyne hydrogenation. Kinetic poisoning experiments revealed that 100% of the V sites are active for hydrogenation.

Original language	English (US)
Pages (from-to)	7325-7328
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	53
DOIs	https://doi.org/10.1039/c7cc01876b
State	Published - 2017

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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Sohn, H., Camacho-Bunquin, J., Langeslay, R. R., Ignacio-De Leon, P. A., Niklas, J., Poluektov, O. G., Liu, C., Connell, J. G., Yang, D., Kropf, J., Kim, H., Stair, P. C., Ferrandon, M., & Delferro, M. (2017). Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes. Chemical Communications, 53(53), 7325-7328. https://doi.org/10.1039/c7cc01876b

@article{e2e39bdf4c3a4503b252a71b5eab04ad,

title = "Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes",

abstract = "A well-defined, isolated, single-site organovanadium(iii) catalyst on SiO2 [(SiO2)V(Mes)(THF)] was synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, 1H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalyst exhibits unprecedented reactivity in liquid-and gas-phase alkene/alkyne hydrogenation. Kinetic poisoning experiments revealed that 100% of the V sites are active for hydrogenation.",

author = "H. Sohn and J. Camacho-Bunquin and Langeslay, {R. R.} and {Ignacio-De Leon}, {P. A.} and J. Niklas and Poluektov, {O. G.} and C. Liu and Connell, {J. G.} and D. Yang and J. Kropf and H. Kim and Stair, {P. C.} and M. Ferrandon and M. Delferro",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2017.",

year = "2017",

doi = "10.1039/c7cc01876b",

language = "English (US)",

volume = "53",

pages = "7325--7328",

journal = "Chemical Communications",

issn = "1359-7345",

number = "53",

}

Sohn, H, Camacho-Bunquin, J, Langeslay, RR, Ignacio-De Leon, PA, Niklas, J, Poluektov, OG, Liu, C, Connell, JG, Yang, D, Kropf, J, Kim, H , Stair, PC, Ferrandon, M & Delferro, M 2017, 'Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes', Chemical Communications, vol. 53, no. 53, pp. 7325-7328. https://doi.org/10.1039/c7cc01876b

TY - JOUR

T1 - Isolated, well-defined organovanadium(III) on silica

T2 - Single-site catalyst for hydrogenation of alkenes and alkynes

AU - Sohn, H.

AU - Camacho-Bunquin, J.

AU - Langeslay, R. R.

AU - Ignacio-De Leon, P. A.

AU - Niklas, J.

AU - Poluektov, O. G.

AU - Liu, C.

AU - Connell, J. G.

AU - Yang, D.

AU - Kropf, J.

AU - Kim, H.

AU - Stair, P. C.

AU - Ferrandon, M.

AU - Delferro, M.

PY - 2017

Y1 - 2017

N2 - A well-defined, isolated, single-site organovanadium(iii) catalyst on SiO2 [(SiO2)V(Mes)(THF)] was synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, 1H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalyst exhibits unprecedented reactivity in liquid-and gas-phase alkene/alkyne hydrogenation. Kinetic poisoning experiments revealed that 100% of the V sites are active for hydrogenation.

AB - A well-defined, isolated, single-site organovanadium(iii) catalyst on SiO2 [(SiO2)V(Mes)(THF)] was synthesized via surface organometallic chemistry, and fully characterized using a combination of analytical and spectroscopic techniques (EA, ICP, 1H NMR, TGA-MS, EPR, XPS, DR-UV/Vis, UV-Raman, DRIFTS, XAS). The catalyst exhibits unprecedented reactivity in liquid-and gas-phase alkene/alkyne hydrogenation. Kinetic poisoning experiments revealed that 100% of the V sites are active for hydrogenation.

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DO - 10.1039/c7cc01876b

M3 - Article

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AN - SCOPUS:85021686198

SN - 1359-7345

VL - 53

SP - 7325

EP - 7328

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Isolated, well-defined organovanadium(III) on silica: Single-site catalyst for hydrogenation of alkenes and alkynes

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