Isolation and Reactivity of Uranyl Superoxide

Dmytro V. Kravchuk, Nicholas N. Dahlen, Samantha J. Kruse, Christos D. Malliakas, Paul M. Shand, Tori Z. Forbes*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Scopus citations


The high radiation field associated with spent nuclear fuel (UIVO2) pellets produces an array of reactive radical species that impact the corrosion and formation of secondary alteration phases. Dioxygen radicals are important as radiolysis products, but the interaction between these reactive oxygen species and UVIO22+ and its effects on the resultant alteration phases is unclear. We report the first example of a UVI superoxide compound and explore its reactivity in the environments relevant to the storage of spent nuclear fuel. We utilized X-ray diffraction and Raman scattering techniques to demonstrate that the uranyl superoxide reacts with CO2 in air to afford a mixed uranyl peroxide/carbonate within 3 days, both in solution and under atmospheric conditions. An additional transformation occurs over the course of 3 months to form a potassium UVI carbonate (grimselite), which also occurs as an alteration product on Chernobyl corium. Our results demonstrate the presence and significance of the superoxide anion in the alteration of spent nuclear fuel and indicate the impact of uranyl superoxide chemistry on high prevalence of carbonate in the secondary phases of spent nuclear fuel.

Original languageEnglish (US)
Pages (from-to)15041-15048
Number of pages8
JournalAngewandte Chemie - International Edition
Issue number27
StatePublished - Jun 25 2021


  • oxygen radicals
  • radiation
  • storage
  • uranyl carbonate
  • uranyl superoxide

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry


Dive into the research topics of 'Isolation and Reactivity of Uranyl Superoxide'. Together they form a unique fingerprint.

Cite this