Isolation and x-ray crystal structure of [Cu(NH3) 4H2O.18-crown-6]n2+[PF 6]2n- a linear face-to-face hydrogen bonded chain copolymer

Howard M. Colquhoun; J. Fraser Stoddart; David J. Williams

doi:10.1039/c39810000849

Isolation and x-ray crystal structure of [Cu(NH₃) ₄H₂O.18-crown-6]_n²⁺[PF ₆]_2n^- a linear face-to-face hydrogen bonded chain copolymer

Howard M. Colquhoun^*, J. Fraser Stoddart, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

X-Ray crystallography reveals that the [aquo-(tetra-ammine)copper] ²⁺ ion forms a chain copolymer with 18-crown-6 in which each individual crown molecule is involved in no fewer than ten hydrogen bonds with four ammine ligands co-ordinated to the copper(II) centres in adjacent ions.

Original language	English (US)
Pages (from-to)	849-850
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/c39810000849
State	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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title = "Isolation and x-ray crystal structure of [Cu(NH3) 4H2O.18-crown-6]n2+[PF 6]2n- a linear face-to-face hydrogen bonded chain copolymer",

abstract = "X-Ray crystallography reveals that the [aquo-(tetra-ammine)copper] 2+ ion forms a chain copolymer with 18-crown-6 in which each individual crown molecule is involved in no fewer than ten hydrogen bonds with four ammine ligands co-ordinated to the copper(II) centres in adjacent ions.",

author = "Colquhoun, {Howard M.} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1981",

doi = "10.1039/c39810000849",

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journal = "Journal of the Chemical Society, Chemical Communications",

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publisher = "Chemical Society",

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T1 - Isolation and x-ray crystal structure of [Cu(NH3) 4H2O.18-crown-6]n2+[PF 6]2n- a linear face-to-face hydrogen bonded chain copolymer

AU - Colquhoun, Howard M.

AU - Stoddart, J. Fraser

AU - Williams, David J.

PY - 1981

Y1 - 1981

N2 - X-Ray crystallography reveals that the [aquo-(tetra-ammine)copper] 2+ ion forms a chain copolymer with 18-crown-6 in which each individual crown molecule is involved in no fewer than ten hydrogen bonds with four ammine ligands co-ordinated to the copper(II) centres in adjacent ions.

AB - X-Ray crystallography reveals that the [aquo-(tetra-ammine)copper] 2+ ion forms a chain copolymer with 18-crown-6 in which each individual crown molecule is involved in no fewer than ten hydrogen bonds with four ammine ligands co-ordinated to the copper(II) centres in adjacent ions.

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Isolation and x-ray crystal structure of [Cu(NH₃) ₄H₂O.18-crown-6]_n²⁺[PF ₆]_2n^- a linear face-to-face hydrogen bonded chain copolymer

Abstract

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