Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

Zhiyong Lu; Rui Wang; Yijun Liao; Omar K. Farha; Wentuan Bi; Thomas R. Sheridan; Kun Zhang; Jiaxin Duan; Jian Liu; Joseph T. Hupp

doi:10.1039/d0cc07974j

Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

Zhiyong Lu^*, Rui Wang, Yijun Liao, Omar K. Farha, Wentuan Bi, Thomas R. Sheridan, Kun Zhang, Jiaxin Duan, Jian Liu, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Review article › peer-review

18 Scopus citations

Abstract

The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy⁴⁻) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy⁴⁻to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous,she-type MOF Zr₆(μ₃-O)₄(μ₃-OH)₄(C₆H₅COO)₃(COO)₃(TBAPy-2)_3/2(NU-601), where TBAPy-2⁴⁻is the 4,5,9,10 isomer of TBAPy⁴⁻.NU-601shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

Original language	English (US)
Pages (from-to)	3571-3574
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	29
DOIs	https://doi.org/10.1039/d0cc07974j
State	Published - Apr 14 2021

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d0cc07974j

Cite this

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title = "Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework",

abstract = "The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy4−) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy4−to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous,she-type MOF Zr6(μ3-O)4(μ3-OH)4(C6H5COO)3(COO)3(TBAPy-2)3/2(NU-601), where TBAPy-24−is the 4,5,9,10 isomer of TBAPy4−.NU-601shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.",

author = "Zhiyong Lu and Rui Wang and Yijun Liao and Farha, {Omar K.} and Wentuan Bi and Sheridan, {Thomas R.} and Kun Zhang and Jiaxin Duan and Jian Liu and Hupp, {Joseph T.}",

note = "Funding Information: This work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (DE-SC0012702). For work specifically on catalytic hydrolysis of nerve-agent simulants we gratefully acknowledge DTRA (grant HDTRA1-18-1-0003). Z. L. gratefully acknowledges support from the National Natural Science Foundation of China (21601047), the Fundamental Research Funds for the Central Universities (2018B17614), and the China Scholarship Council (CSC) (201806715039). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

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doi = "10.1039/d0cc07974j",

language = "English (US)",

volume = "57",

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journal = "Chemical Communications",

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TY - JOUR

T1 - Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

AU - Lu, Zhiyong

AU - Wang, Rui

AU - Liao, Yijun

AU - Farha, Omar K.

AU - Bi, Wentuan

AU - Sheridan, Thomas R.

AU - Zhang, Kun

AU - Duan, Jiaxin

AU - Liu, Jian

AU - Hupp, Joseph T.

N1 - Funding Information: This work was supported as part of the Inorganometallic Catalyst Design Center, an EFRC funded by the U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences (DE-SC0012702). For work specifically on catalytic hydrolysis of nerve-agent simulants we gratefully acknowledge DTRA (grant HDTRA1-18-1-0003). Z. L. gratefully acknowledges support from the National Natural Science Foundation of China (21601047), the Fundamental Research Funds for the Central Universities (2018B17614), and the China Scholarship Council (CSC) (201806715039). Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/4/14

Y1 - 2021/4/14

N2 - The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy4−) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy4−to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous,she-type MOF Zr6(μ3-O)4(μ3-OH)4(C6H5COO)3(COO)3(TBAPy-2)3/2(NU-601), where TBAPy-24−is the 4,5,9,10 isomer of TBAPy4−.NU-601shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

AB - The well-known MOF (metal-organic framework) linker tetrakis(p-benzoate)pyrene (TBAPy4−) lacks steric hindrance between its benzoates. Changing the 1,3,6,8-siting of benzoates in TBAPy4−to 4,5,9,10-siting introduces substantial steric hindrance and, in turn, enables the synthesis of a new hierarchically porous,she-type MOF Zr6(μ3-O)4(μ3-OH)4(C6H5COO)3(COO)3(TBAPy-2)3/2(NU-601), where TBAPy-24−is the 4,5,9,10 isomer of TBAPy4−.NU-601shows high catalytic activity for degradative hydrolysis of a simulant for G-type fluoro-phosphorus nerve agents.

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JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

Abstract

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CCDC 2015124: Experimental Crystal Structure Determination

CCDC 2015123: Experimental Crystal Structure Determination

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Isomer of linker for NU-1000 yields a newshe-type, catalytic, and hierarchically porous, Zr-based metal-organic framework

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CCDC 2015124: Experimental Crystal Structure Determination

CCDC 2015123: Experimental Crystal Structure Determination

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