TY - JOUR
T1 - K
3
B
6
O
10
Cl
T2 - A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge
AU - Wu, Hongping
AU - Pan, Shilie
AU - Poeppelmeier, Kenneth R.
AU - Li, Hongyi
AU - Jia, Dianzeng
AU - Chen, Zhaohui
AU - Fan, Xiaoyun
AU - Yang, Yun
AU - Rondinelli, James M.
AU - Luo, Haosu
PY - 2011/5/25
Y1 - 2011/5/25
N2 -
Introduction of the Cl
-
anion in the borate systems generates a new perovskite-like phase, K
3
B
6
O
10
Cl, which exhibits a large second harmonic response, about four times that of KH
2
PO
4
(KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K
3
B
6
O
10
Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B
6
O
10
] groups and the BX
3
Cl-centered octahedral [ClK
6
] groups linked together through vertices to form the perovskite framework represented by ABX
3
.
AB -
Introduction of the Cl
-
anion in the borate systems generates a new perovskite-like phase, K
3
B
6
O
10
Cl, which exhibits a large second harmonic response, about four times that of KH
2
PO
4
(KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K
3
B
6
O
10
Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B
6
O
10
] groups and the BX
3
Cl-centered octahedral [ClK
6
] groups linked together through vertices to form the perovskite framework represented by ABX
3
.
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UR - http://www.scopus.com/inward/citedby.url?scp=79957693451&partnerID=8YFLogxK
U2 - 10.1021/ja111083x
DO - 10.1021/ja111083x
M3 - Article
C2 - 21534555
AN - SCOPUS:79957693451
VL - 133
SP - 7786
EP - 7790
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 20
ER -