K3B6O10Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

Hongping Wu; Shilie Pan; Kenneth R. Poeppelmeier; Hongyi Li; Dianzeng Jia; Zhaohui Chen; Xiaoyun Fan; Yun Yang; James M. Rondinelli; Haosu Luo

doi:10.1021/ja111083x

K₃B₆O₁₀Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

Hongping Wu, Shilie Pan^*, Kenneth R. Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Yang, James M. Rondinelli, Haosu Luo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

623 Scopus citations

Abstract

Introduction of the Cl^- anion in the borate systems generates a new perovskite-like phase, K₃B₆O₁₀Cl, which exhibits a large second harmonic response, about four times that of KH ₂PO₄ (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K₃B₆O₁₀Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B₆O₁₀] groups and the BX ₃ Cl-centered octahedral [ClK₆] groups linked together through vertices to form the perovskite framework represented by ABX ₃.

Original language	English (US)
Pages (from-to)	7786-7790
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	133
Issue number	20
DOIs	https://doi.org/10.1021/ja111083x
State	Published - May 25 2011

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja111083x

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@article{73b7b0589e1040c98cf9c72d627cc673,

title = "K3B6O10Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge",

abstract = "Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.",

author = "Hongping Wu and Shilie Pan and Poeppelmeier, {Kenneth R.} and Hongyi Li and Dianzeng Jia and Zhaohui Chen and Xiaoyun Fan and Yun Yang and Rondinelli, {James M.} and Haosu Luo",

year = "2011",

month = may,

day = "25",

doi = "10.1021/ja111083x",

language = "English (US)",

volume = "133",

pages = "7786--7790",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "20",

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TY - JOUR

T1 - K3B6O10Cl

T2 - A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

AU - Wu, Hongping

AU - Pan, Shilie

AU - Poeppelmeier, Kenneth R.

AU - Li, Hongyi

AU - Jia, Dianzeng

AU - Chen, Zhaohui

AU - Fan, Xiaoyun

AU - Yang, Yun

AU - Rondinelli, James M.

AU - Luo, Haosu

PY - 2011/5/25

Y1 - 2011/5/25

N2 - Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.

AB - Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.

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DO - 10.1021/ja111083x

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SN - 0002-7863

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EP - 7790

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 20

ER -

K₃B₆O₁₀Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

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CCDC 984161: Experimental Crystal Structure Determination

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K3B6O10Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge

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CCDC 984161: Experimental Crystal Structure Determination

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K₃B₆O₁₀Cl: A new structure analogous to perovskite with a large second harmonic generation response and deep UV absorption edge