Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

J. F. Wang; M. A. Hubbard; Y. Jin; J. T. Lin; T. J. Marks; W. P. Lin; G. K. Wong

doi:10.1117/12.165303

Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

J. F. Wang, M. A. Hubbard, Y. Jin, J. T. Lin, T. J. Marks, W. P. Lin, G. K. Wong

Chemistry

Research output: Contribution to journal › Conference article › peer-review

4 Scopus citations

Abstract

Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve T_g values approaching + 240°C and exceptional SHG temporal stability.

Original language	English (US)
Pages (from-to)	62-68
Number of pages	7
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	2025
DOIs	https://doi.org/10.1117/12.165303
State	Published - Dec 16 1993
Event	Nonlinear Optical Properties of Organic Materials VI 1993 - San Diego, United States Duration: Jul 11 1993 → Jul 16 1993

Funding

We thank NSF (Grant DMR 9120521) through Northwestern University Materials Research Center and AFOSR (Contract 90-0071) for support of this research. J.T.L. thanks Academia Sinica (ROC) for a sabbatical leave, and M.A.H. thanks the AFOSR for a Laboratory Graduate Fellowship.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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10.1117/12.165303

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Wang, J. F., Hubbard, M. A., Jin, Y., Lin, J. T., Marks, T. J., Lin, W. P., & Wong, G. K. (1993). Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems. Proceedings of SPIE - The International Society for Optical Engineering, 2025, 62-68. https://doi.org/10.1117/12.165303

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abstract = "Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.",

author = "Wang, {J. F.} and Hubbard, {M. A.} and Y. Jin and Lin, {J. T.} and Marks, {T. J.} and Lin, {W. P.} and Wong, {G. K.}",

note = "Funding Information: We thank NSF (Grant DMR 9120521) through Northwestern University Materials Research Center and AFOSR (Contract 90-0071) for support of this research. J.T.L. thanks Academia Sinica (ROC) for a sabbatical leave, and M.A.H. thanks the AFOSR for a Laboratory Graduate Fellowship. Publisher Copyright: {\textcopyright} 1993 SPIE. All rights reserved.; Nonlinear Optical Properties of Organic Materials VI 1993 ; Conference date: 11-07-1993 Through 16-07-1993",

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Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems. / Wang, J. F.; Hubbard, M. A.; Jin, Y. et al.
In: Proceedings of SPIE - The International Society for Optical Engineering, Vol. 2025, 16.12.1993, p. 62-68.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

AU - Wang, J. F.

AU - Hubbard, M. A.

AU - Jin, Y.

AU - Lin, J. T.

AU - Marks, T. J.

AU - Lin, W. P.

AU - Wong, G. K.

N1 - Funding Information: We thank NSF (Grant DMR 9120521) through Northwestern University Materials Research Center and AFOSR (Contract 90-0071) for support of this research. J.T.L. thanks Academia Sinica (ROC) for a sabbatical leave, and M.A.H. thanks the AFOSR for a Laboratory Graduate Fellowship. Publisher Copyright: © 1993 SPIE. All rights reserved.

PY - 1993/12/16

Y1 - 1993/12/16

N2 - Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.

AB - Two complementary approaches to the construction of poled, crosslinked second-order polymeric NLO materials are discussed. In the first, poly(p-hydroxystyrene) is functionalized with a nitroaniline chromophore having a protectable hydroxyl group for hydrogen bonding or epoxy crosslinking. Chromophore immobilization is most effective when crosslinks can be made directly at the chromophore substituent and when multifunctional crosslinking agents are employed. The second approach shows that matrices prepared from an aryldiamine chromophore and a bismaleimide co-monomer can achieve Tg values approaching + 240°C and exceptional SHG temporal stability.

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JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

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Knowledge base for the design of high performance second-order NLO materials. Architecture - Relaxation correlations in new crosslinked poled polymer systems

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