K10M4Sn4S17 (M = Mn, Fe, Co, Zn): Soluble quaternary sulfides with the discrete [M4Sn 4S17]10- supertetrahedral clusters

Oleg Palchik; Ratnasabapathy G. Iyer; J. H. Liao; Mercouri G. Kanatzidis

doi:10.1021/ic034600l

K₁₀M₄Sn₄S₁₇ (M = Mn, Fe, Co, Zn): Soluble quaternary sulfides with the discrete [M₄Sn ₄S₁₇]^10- supertetrahedral clusters

Oleg Palchik, Ratnasabapathy G. Iyer, J. H. Liao, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

96 Scopus citations

Abstract

Four cubic compounds are reported that contain the supertetrahedral cluster [M₄Sn₄S₁₇]^10- where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (μ₄-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS₄] ^4- fragments to complete the structure.

Original language	English (US)
Pages (from-to)	5052-5054
Number of pages	3
Journal	Inorganic chemistry
Volume	42
Issue number	17
DOIs	https://doi.org/10.1021/ic034600l
State	Published - Aug 25 2003

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17]10- where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (μ4-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS4] 4- fragments to complete the structure.",

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AU - Iyer, Ratnasabapathy G.

AU - Liao, J. H.

AU - Kanatzidis, Mercouri G.

PY - 2003/8/25

Y1 - 2003/8/25

N2 - Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17]10- where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (μ4-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS4] 4- fragments to complete the structure.

AB - Four cubic compounds are reported that contain the supertetrahedral cluster [M4Sn4S17]10- where M = Mn, Fe, Co, Zn. The cluster features a central quadruply bridging sulfide ion (μ4-S) that holds together four divalent M atoms in a tetrahedral arrangement. This core is capped with four tridentate [SnS4] 4- fragments to complete the structure.

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K₁₀M₄Sn₄S₁₇ (M = Mn, Fe, Co, Zn): Soluble quaternary sulfides with the discrete [M₄Sn ₄S₁₇]^10- supertetrahedral clusters

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