K2Cu5Te5, a Novel Mixed‐Valence Layered Compound with Metallic Properties

Younbong Park; Mercouri G. Kanatzidis; Carl R. Kannewurf; Donald C. Degroot; Jon Schindler

doi:10.1002/anie.199113251

K₂Cu₅Te₅, a Novel Mixed‐Valence Layered Compound with Metallic Properties

Younbong Park, Mercouri G. Kanatzidis^*, Carl R. Kannewurf, Donald C. Degroot, Jon Schindler

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Edge‐sharing rhombic [Cu₂Te₂] units form the building blocks in the corrugated anionic [Cu₅Te₅] n2n− layers (see the sketch at the right) in mixed‐valent K₂Cu₅Te₅—a metallic conductor of the p type. K₂Cu₅Te₅ is formed on treatment of Cu with K₂Te_x (x ≈ 4) at 350°C in vacuum as black crystals and is stable to air and moisture. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1325-1328
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	10
DOIs	https://doi.org/10.1002/anie.199113251
State	Published - Oct 1991

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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title = "K2Cu5Te5, a Novel Mixed‐Valence Layered Compound with Metallic Properties",

abstract = "Edge‐sharing rhombic [Cu2Te2] units form the building blocks in the corrugated anionic [Cu5Te5] n2n− layers (see the sketch at the right) in mixed‐valent K2Cu5Te5—a metallic conductor of the p type. K2Cu5Te5 is formed on treatment of Cu with K2Tex (x ≈ 4) at 350°C in vacuum as black crystals and is stable to air and moisture. (Figure Presented.)",

author = "Younbong Park and Kanatzidis, {Mercouri G.} and Kannewurf, {Carl R.} and Degroot, {Donald C.} and Jon Schindler",

year = "1991",

month = oct,

doi = "10.1002/anie.199113251",

language = "English (US)",

volume = "30",

pages = "1325--1328",

journal = "Angewandte Chemie - International Edition",

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T1 - K2Cu5Te5, a Novel Mixed‐Valence Layered Compound with Metallic Properties

AU - Park, Younbong

AU - Kanatzidis, Mercouri G.

AU - Kannewurf, Carl R.

AU - Degroot, Donald C.

AU - Schindler, Jon

PY - 1991/10

Y1 - 1991/10

N2 - Edge‐sharing rhombic [Cu2Te2] units form the building blocks in the corrugated anionic [Cu5Te5] n2n− layers (see the sketch at the right) in mixed‐valent K2Cu5Te5—a metallic conductor of the p type. K2Cu5Te5 is formed on treatment of Cu with K2Tex (x ≈ 4) at 350°C in vacuum as black crystals and is stable to air and moisture. (Figure Presented.)

AB - Edge‐sharing rhombic [Cu2Te2] units form the building blocks in the corrugated anionic [Cu5Te5] n2n− layers (see the sketch at the right) in mixed‐valent K2Cu5Te5—a metallic conductor of the p type. K2Cu5Te5 is formed on treatment of Cu with K2Tex (x ≈ 4) at 350°C in vacuum as black crystals and is stable to air and moisture. (Figure Presented.)

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K₂Cu₅Te₅, a Novel Mixed‐Valence Layered Compound with Metallic Properties

Abstract

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