K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

Nan Ding; Duck Young Chung; Mercouri G. Kanatzidis

doi:10.1039/b402686a

K₆Cd₄Sn₃Se₁₃: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd₄Sn₄Se₁₇]¹⁰⁻ cluster

Nan Ding, Duck Young Chung, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

K₆Cd₄Sn₃Se₁₃ forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd₄Sn₃Se₁₃]⁶⁻ cluster which formally derives from a [Cd₄Sn₄Se₁₇]¹⁰⁻ via elimination of one [SnSe₄]⁴⁻ anion. K₆Cd₄Sn₃Se₁₃ exhibits facile ion-exchange properties with suitably sized cations.

Original language	English (US)
Pages (from-to)	1170-1171
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	10
DOIs	https://doi.org/10.1039/b402686a
State	Published - Jan 1 2004

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b402686a

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AU - Kanatzidis, Mercouri G.

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N2 - K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10− via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

AB - K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10− via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

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K₆Cd₄Sn₃Se₁₃: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd₄Sn₄Se₁₇]¹⁰⁻ cluster

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