K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10− cluster

Nan Ding, Duck Young Chung, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

71 Scopus citations

Abstract

K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10− via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-exchange properties with suitably sized cations.

Original languageEnglish (US)
Pages (from-to)1170-1171
Number of pages2
JournalChemical Communications
Volume4
Issue number10
DOIs
StatePublished - Jan 1 2004

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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