Large-Area Patterning of Metal Nanostructures by Dip-Pen Nanodisplacement Lithography for Optical Applications

Lina Chen, Xiaoling Wei, Xuechang Zhou, Zhuang Xie, Kan Li, Qifeng Ruan, Chaojian Chen, Jianfang Wang, Chad A. Mirkin, Zijian Zheng*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

30 Scopus citations

Abstract

Au nanostructures are remarkably important in a wide variety of fields for decades. The fabrication of Au nanostructures typically requires time-consuming and expensive electron-beam lithography (EBL) that operates in vacuum. To address this challenge, this paper reports the development of massive dip-pen nanodisplacement lithography (DNL) as a desktop fabrication tool, which allows high-throughput and rational design of arbitrary Au nanopatterns in ambient condition. Large-area (1 cm2) and uniform (<10% variation) Au nanostructures as small as 70 nm are readily fabricated, with a throughput 100-fold higher than that of conventional EBL. As a proof-of-concept of the applications in the opitcal field, we fabricate discrete Au nanorod arrays that show significant plasmonic resonance in the visible range, and interconnected Au nanomeshes that are used for transparent conductive electrode of solar cells.

Original languageEnglish (US)
Article number1702003
JournalSmall
Volume13
Issue number43
DOIs
StatePublished - Nov 20 2017

Funding

L.N.C. and X.L.W. contributed equally to this work. Z.J.Z. acknowledges the Hong Kong Polytechnic University (4-BCBM, 1ZE27) and General Research Fund of Hong Kong (PolyU 153202/16P) for financial support of this work. C.A.M. and Z.X. acknowledge support by the AFOSR under award FA9550-16-1-0150 and the National Science Foundation under award DBI-1353682. The authors thank Dr. Danqing Liu and Prof. Qian Miao at the Chinese University of Hong Kong for their help with Au film evaporation on silicon substrate.

Keywords

  • nanofabrication
  • polymer brush
  • scanning probe lithography
  • solar cells
  • transparent conductive electrodes

ASJC Scopus subject areas

  • General Chemistry
  • Engineering (miscellaneous)
  • Biotechnology
  • General Materials Science
  • Biomaterials

Fingerprint

Dive into the research topics of 'Large-Area Patterning of Metal Nanostructures by Dip-Pen Nanodisplacement Lithography for Optical Applications'. Together they form a unique fingerprint.

Cite this