Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Hea Jung Park; Monica C. So; David Gosztola; Gary P. Wiederrecht; Jonathan D. Emery; Alex B.F. Martinson; Süleyman Er; Christopher E. Wilmer; Nicolaas A. Vermeulen; Alán Aspuru-Guzik; J. Fraser Stoddart; Omar K. Farha; Joseph T. Hupp

doi:10.1021/acsami.6b03307

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Hea Jung Park, Monica C. So, David Gosztola, Gary P. Wiederrecht, Jonathan D. Emery, Alex B.F. Martinson, Süleyman Er, Christopher E. Wilmer, Nicolaas A. Vermeulen, Alán Aspuru-Guzik, J. Fraser Stoddart, Omar K. Farha^*, Joseph T. Hupp

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl₄, PDIOPh₂) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl₄ and PDIOPh₂) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

Original language	English (US)
Pages (from-to)	24983-24988
Number of pages	6
Journal	ACS Applied Materials and Interfaces
Volume	8
Issue number	38
DOIs	https://doi.org/10.1021/acsami.6b03307
State	Published - Sep 28 2016

Funding

acknowledge support from the Center for Excitonics and Energy Frontier Research Center funded by the U.S. Department of Energy under Award DE-SC0001088. Computations were run on the Harvard Universitys dyssey cluster, supported by the Research Computing Group of the FAS Division of Science.

Keywords

directional energy transfer
energy cascade
exciton migration
layer-by-Layer
multizone MOF-like film

ASJC Scopus subject areas

General Materials Science

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/acsami.6b03307

Cite this

Park, H. J., So, M. C., Gosztola, D., Wiederrecht, G. P., Emery, J. D., Martinson, A. B. F., Er, S., Wilmer, C. E., Vermeulen, N. A., Aspuru-Guzik, A., Stoddart, J. F., Farha, O. K., & Hupp, J. T. (2016). Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer. ACS Applied Materials and Interfaces, 8(38), 24983-24988. https://doi.org/10.1021/acsami.6b03307

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title = "Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer",

abstract = "We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.",

keywords = "directional energy transfer, energy cascade, exciton migration, layer-by-Layer, multizone MOF-like film",

author = "Park, {Hea Jung} and So, {Monica C.} and David Gosztola and Wiederrecht, {Gary P.} and Emery, {Jonathan D.} and Martinson, {Alex B.F.} and S{\"u}leyman Er and Wilmer, {Christopher E.} and Vermeulen, {Nicolaas A.} and Al{\'a}n Aspuru-Guzik and Stoddart, {J. Fraser} and Farha, {Omar K.} and Hupp, {Joseph T.}",

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year = "2016",

month = sep,

day = "28",

doi = "10.1021/acsami.6b03307",

language = "English (US)",

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Park, HJ, So, MC, Gosztola, D, Wiederrecht, GP, Emery, JD, Martinson, ABF, Er, S, Wilmer, CE, Vermeulen, NA, Aspuru-Guzik, A, Stoddart, JF, Farha, OK & Hupp, JT 2016, 'Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer', ACS Applied Materials and Interfaces, vol. 8, no. 38, pp. 24983-24988. https://doi.org/10.1021/acsami.6b03307

Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer. / Park, Hea Jung; So, Monica C.; Gosztola, David et al.
In: ACS Applied Materials and Interfaces, Vol. 8, No. 38, 28.09.2016, p. 24983-24988.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials

T2 - Solar Energy Capture and Directional Energy Transfer

AU - Park, Hea Jung

AU - So, Monica C.

AU - Gosztola, David

AU - Wiederrecht, Gary P.

AU - Emery, Jonathan D.

AU - Martinson, Alex B.F.

AU - Er, Süleyman

AU - Wilmer, Christopher E.

AU - Vermeulen, Nicolaas A.

AU - Aspuru-Guzik, Alán

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

AU - Hupp, Joseph T.

PY - 2016/9/28

Y1 - 2016/9/28

N2 - We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

AB - We demonstrate that thin films of metal-organic framework (MOF)-like materials, containing two perylenediimides (PDICl4, PDIOPh2) and a squaraine dye (S1), can be fabricated by layer-by-layer assembly (LbL). Interestingly, these LbL films absorb across the visible light region (400-750 nm) and facilitate directional energy transfer. Due to the high spectral overlap and oriented transition dipole moments of the donor (PDICl4 and PDIOPh2) and acceptor (S1) components, directional long-range energy transfer from the bluest to reddest absorber was successfully demonstrated in the multicomponent MOF-like films. These findings have significant implications for the development of solar energy conversion devices based on MOFs.

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KW - energy cascade

KW - exciton migration

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JO - ACS Applied Materials and Interfaces

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Layer-by-Layer Assembled Films of Perylene Diimide- and Squaraine-Containing Metal-Organic Framework-like Materials: Solar Energy Capture and Directional Energy Transfer

Abstract

Funding

Keywords

ASJC Scopus subject areas

UN SDGs

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