Abstract
The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1809-1811 |
| Number of pages | 3 |
| Journal | Inorganic chemistry |
| Volume | 39 |
| Issue number | 8 |
| DOIs | |
| State | Published - Apr 17 2000 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Dive into the research topics of 'Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands'. Together they form a unique fingerprint.Datasets
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CCDC 1424786: Experimental Crystal Structure Determination
Mironov, Y. V. (Creator), Fedorov, V. E. (Creator), McLauchlan, C. C. (Creator) & Ibers, J. A. (Creator), Cambridge Crystallographic Data Centre, 2015
DOI: 10.5517/cc1jtlvs, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jtlvs&sid=DataCite
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CCDC 1424787: Experimental Crystal Structure Determination
Mironov, Y. V. (Creator), Fedorov, V. E. (Creator), McLauchlan, C. C. (Creator) & Ibers, J. A. (Creator), Cambridge Crystallographic Data Centre, 2015
DOI: 10.5517/cc1jtlwt, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jtlwt&sid=DataCite
Dataset