Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Yuri V. Mironov, Vladimir E. Fedorov, Craig C. McLauchlan, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.

Original languageEnglish (US)
Pages (from-to)1809-1811
Number of pages3
JournalInorganic chemistry
Volume39
Issue number8
DOIs
StatePublished - Apr 17 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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