Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Yuri V. Mironov; Vladimir E. Fedorov; Craig C. McLauchlan; James A. Ibers

doi:10.1021/ic990936c

Layered K₄[Re₆S₁₀(CN)₂] and chainlike K₄[Re₆Se₁₀(CN)₄]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Yuri V. Mironov, Vladimir E. Fedorov, Craig C. McLauchlan, James A. Ibers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The chalcocyanide compounds K₄[Re₆S₁₀(CN)₂] (1) and K₄[Re₆Se₁₀(CN)₄] (2) have been synthesized from ReQ₂ (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re₆Q₈]²⁺ cores and terminal CN^- ligands.

Original language	English (US)
Pages (from-to)	1809-1811
Number of pages	3
Journal	Inorganic chemistry
Volume	39
Issue number	8
DOIs	https://doi.org/10.1021/ic990936c
State	Published - Apr 17 2000
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic990936c

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title = "Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands",

abstract = "The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.",

author = "Mironov, {Yuri V.} and Fedorov, {Vladimir E.} and McLauchlan, {Craig C.} and Ibers, {James A.}",

year = "2000",

month = apr,

day = "17",

doi = "10.1021/ic990936c",

language = "English (US)",

volume = "39",

pages = "1809--1811",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]

T2 - New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

AU - Mironov, Yuri V.

AU - Fedorov, Vladimir E.

AU - McLauchlan, Craig C.

AU - Ibers, James A.

PY - 2000/4/17

Y1 - 2000/4/17

N2 - The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.

AB - The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.

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U2 - 10.1021/ic990936c

DO - 10.1021/ic990936c

M3 - Article

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AN - SCOPUS:0034678257

SN - 0020-1669

VL - 39

SP - 1809

EP - 1811

JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 8

ER -

Layered K₄[Re₆S₁₀(CN)₂] and chainlike K₄[Re₆Se₁₀(CN)₄]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Abstract

ASJC Scopus subject areas

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CCDC 1424786: Experimental Crystal Structure Determination

CCDC 1424787: Experimental Crystal Structure Determination

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Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 1424786: Experimental Crystal Structure Determination

CCDC 1424787: Experimental Crystal Structure Determination

Cite this

Layered K₄[Re₆S₁₀(CN)₂] and chainlike K₄[Re₆Se₁₀(CN)₄]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands