Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Yuri V. Mironov; Vladimir E. Fedorov; Craig C. McLauchlan; James A. Ibers

doi:10.1021/ic990936c

Layered K₄[Re₆S₁₀(CN)₂] and chainlike K₄[Re₆Se₁₀(CN)₄]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

Yuri V. Mironov, Vladimir E. Fedorov, Craig C. McLauchlan, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The chalcocyanide compounds K₄[Re₆S₁₀(CN)₂] (1) and K₄[Re₆Se₁₀(CN)₄] (2) have been synthesized from ReQ₂ (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re₆Q₈]²⁺ cores and terminal CN^- ligands.

Original language	English (US)
Pages (from-to)	1809-1811
Number of pages	3
Journal	Inorganic chemistry
Volume	39
Issue number	8
DOIs	https://doi.org/10.1021/ic990936c
State	Published - Apr 17 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic990936c

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title = "Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]: New types of chalcocyanide cluster compounds with bridging chalcogenide ligands",

abstract = "The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.",

author = "Mironov, {Yuri V.} and Fedorov, {Vladimir E.} and McLauchlan, {Craig C.} and Ibers, {James A.}",

year = "2000",

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doi = "10.1021/ic990936c",

language = "English (US)",

volume = "39",

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T1 - Layered K4[Re6S10(CN)2] and chainlike K4[Re6Se10(CN)4]

T2 - New types of chalcocyanide cluster compounds with bridging chalcogenide ligands

AU - Mironov, Yuri V.

AU - Fedorov, Vladimir E.

AU - McLauchlan, Craig C.

AU - Ibers, James A.

PY - 2000/4/17

Y1 - 2000/4/17

N2 - The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.

AB - The chalcocyanide compounds K4[Re6S10(CN)2] (1) and K4[Re6Se10(CN)4] (2) have been synthesized from ReQ2 (Q = S, Se) and molten KCN at high temperatures and characterized by single-crystal X-ray diffraction methods. Both compounds exhibit bridging chalcogenido ligands between [Re6Q8]2+ cores and terminal CN- ligands.

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JF - Inorganic Chemistry

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