Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Zhijie Chen; Penghao Li; Xingjie Wang; Ken Ichi Otake; Xuan Zhang; Lee Robison; Ahmet Atilgan; Timur Islamoglu; Morgan G. Hall; Gregory W. Peterson; J. Fraser Stoddart; Omar K. Farha

doi:10.1021/jacs.9b06179

Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Zhijie Chen, Penghao Li, Xingjie Wang, Ken Ichi Otake, Xuan Zhang, Lee Robison, Ahmet Atilgan, Timur Islamoglu, Morgan G. Hall, Gregory W. Peterson, J. Fraser Stoddart, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr₆ nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).

Original language	English (US)
Pages (from-to)	12229-12235
Number of pages	7
Journal	Journal of the American Chemical Society
Volume	141
Issue number	31
DOIs	https://doi.org/10.1021/jacs.9b06179
State	Published - Aug 7 2019

Funding

O.K.F. gratefully acknowledges support from the Defense Threat Reduction Agency (HDTRA1-18-1-0003 for catalysis and HDTRA1-19-1-0007 for MOF synthesis). This work made use of the EPIC facility of Northwestern University’s NUANCE Center, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF NNCI-1542205); the MRSEC program (NSF DMR-1720139) at the Materials Research Center; the International Institute for Nanotechnology (IIN); the Keck Foundation; and the State of Illinois through the IIN. This work made use of the IMSERC at Northwestern University, which has received support from the NSF (CHE-1048773 and DMR0521267); the SHyNE Resource (NSF NNCI-1542205); the State of Illinois, and the IIN. P.L. and J.F.S. acknowledge the Joint Center of Excellence in Integrated Nano-Systems (JCIN) at King Abdulaziz City for Science and Technology (KACST) and Northwestern University (NU). G.W.P. and M.H. gratefully acknowledge support from the Defense Threat Reduction Agency under Grant CB3934 for the hydrolysis of GD. We thanks Margaret E. Schott for the proofreading of this paper.

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.9b06179

Cite this

Chen, Z., Li, P., Wang, X., Otake, K. I., Zhang, X., Robison, L., Atilgan, A., Islamoglu, T., Hall, M. G., Peterson, G. W., Stoddart, J. F., & Farha, O. K. (2019). Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks. Journal of the American Chemical Society, 141(31), 12229-12235. https://doi.org/10.1021/jacs.9b06179

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title = "Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks",

abstract = "Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).",

author = "Zhijie Chen and Penghao Li and Xingjie Wang and Otake, {Ken Ichi} and Xuan Zhang and Lee Robison and Ahmet Atilgan and Timur Islamoglu and Hall, {Morgan G.} and Peterson, {Gregory W.} and Stoddart, {J. Fraser} and Farha, {Omar K.}",

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language = "English (US)",

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AU - Chen, Zhijie

AU - Li, Penghao

AU - Wang, Xingjie

AU - Otake, Ken Ichi

AU - Zhang, Xuan

AU - Robison, Lee

AU - Atilgan, Ahmet

AU - Islamoglu, Timur

AU - Hall, Morgan G.

AU - Peterson, Gregory W.

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

PY - 2019/8/7

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N2 - Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).

AB - Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).

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Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Abstract

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ASJC Scopus subject areas

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CCDC 1908941: Experimental Crystal Structure Determination

CCDC 1908939: Experimental Crystal Structure Determination

CCDC 1908940: Experimental Crystal Structure Determination

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Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Abstract

Funding

ASJC Scopus subject areas

Access to Document

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Datasets

CCDC 1908941: Experimental Crystal Structure Determination

CCDC 1908939: Experimental Crystal Structure Determination

CCDC 1908940: Experimental Crystal Structure Determination

Cite this