Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Zhijie Chen; Penghao Li; Xingjie Wang; Ken Ichi Otake; Xuan Zhang; Lee Robison; Ahmet Atilgan; Timur Islamoglu; Morgan G. Hall; Gregory W. Peterson; J. Fraser Stoddart; Omar K. Farha

doi:10.1021/jacs.9b06179

Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks

Zhijie Chen, Penghao Li, Xingjie Wang, Ken Ichi Otake, Xuan Zhang, Lee Robison, Ahmet Atilgan, Timur Islamoglu, Morgan G. Hall, Gregory W. Peterson, J. Fraser Stoddart, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr₆ nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).

Original language	English (US)
Pages (from-to)	12229-12235
Number of pages	7
Journal	Journal of the American Chemical Society
Volume	141
Issue number	31
DOIs	https://doi.org/10.1021/jacs.9b06179
State	Published - Aug 7 2019

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Chen, Z., Li, P., Wang, X., Otake, K. I., Zhang, X., Robison, L., Atilgan, A., Islamoglu, T., Hall, M. G., Peterson, G. W., Stoddart, J. F., & Farha, O. K. (2019). Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks. Journal of the American Chemical Society, 141(31), 12229-12235. https://doi.org/10.1021/jacs.9b06179

Chen, Zhijie ; Li, Penghao ; Wang, Xingjie ; Otake, Ken Ichi ; Zhang, Xuan ; Robison, Lee ; Atilgan, Ahmet ; Islamoglu, Timur ; Hall, Morgan G. ; Peterson, Gregory W. ; Stoddart, J. Fraser ; Farha, Omar K. / Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 31. pp. 12229-12235.

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title = "Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks",

abstract = "Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).",

author = "Zhijie Chen and Penghao Li and Xingjie Wang and Otake, {Ken Ichi} and Xuan Zhang and Lee Robison and Ahmet Atilgan and Timur Islamoglu and Hall, {Morgan G.} and Peterson, {Gregory W.} and Stoddart, {J. Fraser} and Farha, {Omar K.}",

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Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks. / Chen, Zhijie; Li, Penghao; Wang, Xingjie; Otake, Ken Ichi; Zhang, Xuan; Robison, Lee; Atilgan, Ahmet; Islamoglu, Timur; Hall, Morgan G.; Peterson, Gregory W.; Stoddart, J. Fraser ; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 141, No. 31, 07.08.2019, p. 12229-12235.

Research output: Contribution to journal › Article › peer-review

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AU - Li, Penghao

AU - Wang, Xingjie

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AU - Zhang, Xuan

AU - Robison, Lee

AU - Atilgan, Ahmet

AU - Islamoglu, Timur

AU - Hall, Morgan G.

AU - Peterson, Gregory W.

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

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