Abstract
Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).
Original language | English (US) |
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Pages (from-to) | 12229-12235 |
Number of pages | 7 |
Journal | Journal of the American Chemical Society |
Volume | 141 |
Issue number | 31 |
DOIs | |
State | Published - Aug 7 2019 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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CCDC 1908939: Experimental Crystal Structure Determination
Chen, Z. (Contributor), Li, P. (Contributor), Wang, X. (Contributor), Otake, K. (Contributor), Zhang, X. (Contributor), Robison, L. (Contributor), Atilgan, A. (Contributor), Islamoglu, T. (Contributor), Hall, M. G. (Contributor), Peterson, G. W. (Contributor), Stoddart, J. F. (Contributor) & Farha, O. K. (Contributor), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc222dp8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc222dp8&sid=DataCite
Dataset
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CCDC 1908941: Experimental Crystal Structure Determination
Chen, Z. (Contributor), Li, P. (Contributor), Wang, X. (Contributor), Otake, K. (Contributor), Zhang, X. (Contributor), Robison, L. (Contributor), Atilgan, A. (Contributor), Islamoglu, T. (Contributor), Hall, M. G. (Contributor), Peterson, G. W. (Contributor), Stoddart, J. F. (Contributor) & Farha, O. K. (Contributor), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc222drb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc222drb&sid=DataCite
Dataset
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CCDC 1908940: Experimental Crystal Structure Determination
Chen, Z. (Contributor), Li, P. (Contributor), Wang, X. (Contributor), Otake, K. (Contributor), Zhang, X. (Contributor), Robison, L. (Contributor), Atilgan, A. (Contributor), Islamoglu, T. (Contributor), Hall, M. G. (Contributor), Peterson, G. W. (Contributor), Stoddart, J. F. (Contributor) & Farha, O. K. (Contributor), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc222dq9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc222dq9&sid=DataCite
Dataset