TY - JOUR
T1 - Ligand-Directed Reticular Synthesis of Catalytically Active Missing Zirconium-Based Metal-Organic Frameworks
AU - Chen, Zhijie
AU - Li, Penghao
AU - Wang, Xingjie
AU - Otake, Ken Ichi
AU - Zhang, Xuan
AU - Robison, Lee
AU - Atilgan, Ahmet
AU - Islamoglu, Timur
AU - Hall, Morgan G.
AU - Peterson, Gregory W.
AU - Stoddart, J. Fraser
AU - Farha, Omar K.
PY - 2019/8/7
Y1 - 2019/8/7
N2 - Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).
AB - Zirconium-based metal-organic frameworks (Zr-MOFs) based on edge-transitive nets such as fcu, spn, she, csq, and ftw with diverse potential applications have been widely reported. Zr-MOFs based on the highly connected 6,12-connected alb net, however, remain absent on account of synthetic challenges. Herein we report the ligand-directed reticular syntheses and isoreticular expansion of a series of Zr-MOFs with the edge-transitive alb net from 12-connected hexagonal-prismatic Zr6 nodes and 6-connected trigonal-prismatic linkers, i.e., microporous NU-1600, mesoporous NU-1601, and mesoporous NU-1602. These Zr-MOFs exhibit remarkable activities toward the destruction of a nerve agent (soman) and a nerve agent simulant (DMNP).
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U2 - 10.1021/jacs.9b06179
DO - 10.1021/jacs.9b06179
M3 - Article
C2 - 31343872
AN - SCOPUS:85071081207
VL - 141
SP - 12229
EP - 12235
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 31
ER -