Light-harvesting metal-organic frameworks (MOFs): Efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs

Chang Yeon Lee; Omar K. Farha; Bong Jin Hong; Amy A. Sarjeant; Sonbinh T. Nguyen; Joseph T. Hupp

doi:10.1021/ja206029a

Light-harvesting metal-organic frameworks (MOFs): Efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs

Chang Yeon Lee, Omar K. Farha^*, Bong Jin Hong, Amy A. Sarjeant, Sonbinh T. Nguyen, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

720 Scopus citations

Abstract

A pillared-paddlewheel type metal-organic framework material featuring bodipy- and porphyrin-based struts, and capable of harvesting light across the entire visible spectrum, has been synthesized. Efficient-essentially quantitative-strut-to-strut energy transfer (antenna behavior) was observed for the well-organized donor-acceptor assembly consituting the ordered MOF structure.

Original language	English (US)
Pages (from-to)	15858-15861
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	40
DOIs	https://doi.org/10.1021/ja206029a
State	Published - Oct 12 2011

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja206029a

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title = "Light-harvesting metal-organic frameworks (MOFs): Efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs",

abstract = "A pillared-paddlewheel type metal-organic framework material featuring bodipy- and porphyrin-based struts, and capable of harvesting light across the entire visible spectrum, has been synthesized. Efficient-essentially quantitative-strut-to-strut energy transfer (antenna behavior) was observed for the well-organized donor-acceptor assembly consituting the ordered MOF structure.",

author = "Lee, {Chang Yeon} and Farha, {Omar K.} and Hong, {Bong Jin} and Sarjeant, {Amy A.} and Nguyen, {Sonbinh T.} and Hupp, {Joseph T.}",

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AU - Farha, Omar K.

AU - Hong, Bong Jin

AU - Sarjeant, Amy A.

AU - Nguyen, Sonbinh T.

AU - Hupp, Joseph T.

PY - 2011/10/12

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N2 - A pillared-paddlewheel type metal-organic framework material featuring bodipy- and porphyrin-based struts, and capable of harvesting light across the entire visible spectrum, has been synthesized. Efficient-essentially quantitative-strut-to-strut energy transfer (antenna behavior) was observed for the well-organized donor-acceptor assembly consituting the ordered MOF structure.

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Light-harvesting metal-organic frameworks (MOFs): Efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs

Abstract

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CCDC 860289: Experimental Crystal Structure Determination

CCDC 860288: Experimental Crystal Structure Determination

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Light-harvesting metal-organic frameworks (MOFs): Efficient strut-to-strut energy transfer in bodipy and porphyrin-based MOFs

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 860289: Experimental Crystal Structure Determination

CCDC 860288: Experimental Crystal Structure Determination

Cite this