Linkage isomerism in a face-centered cubic Cu6Cr 8(CN)24 cluster with an S = 15 ground state

T. David Harris; Jeffrey R. Long

doi:10.1039/b615141h

Linkage isomerism in a face-centered cubic Cu₆Cr ₈(CN)₂₄ cluster with an S = 15 ground state

T. David Harris, Jeffrey R. Long^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Access to the new complex [TpCr(CN)₃]^- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp₈(H₂O)₆Cu₆Cr₈(CN) ₂₄]⁴⁺, both exhibiting an S = 15 ground state.

Original language	English (US)
Pages (from-to)	1360-1362
Number of pages	3
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b615141h
State	Published - Jan 1 2007

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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@article{e114355b205649b89e2d4150e918d6d2,

title = "Linkage isomerism in a face-centered cubic Cu6Cr 8(CN)24 cluster with an S = 15 ground state",

abstract = "Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN) 24]4+, both exhibiting an S = 15 ground state.",

author = "Harris, {T. David} and Long, {Jeffrey R.}",

year = "2007",

month = jan,

day = "1",

doi = "10.1039/b615141h",

language = "English (US)",

pages = "1360--1362",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Linkage isomerism in a face-centered cubic Cu6Cr 8(CN)24 cluster with an S = 15 ground state

AU - Harris, T. David

AU - Long, Jeffrey R.

PY - 2007/1/1

Y1 - 2007/1/1

N2 - Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN) 24]4+, both exhibiting an S = 15 ground state.

AB - Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN) 24]4+, both exhibiting an S = 15 ground state.

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U2 - 10.1039/b615141h

DO - 10.1039/b615141h

M3 - Article

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SN - 1359-7345

SP - 1360

EP - 1362

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Linkage isomerism in a face-centered cubic Cu₆Cr ₈(CN)₂₄ cluster with an S = 15 ground state

Abstract

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