Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer

Richard P Van Duyne; Charles N. Reilley

doi:10.1021/ac60309a027

Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer

Richard P Van Duyne^*, Charles N. Reilley

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

A simple method is presented for analyzing the temperature dependence of pseudo first order chemical reaction(s) coupled to a heterogeneous charge transfer process. The temperature dependent factors associated with the mass transport and heterogeneous charge transfer processes have been specifically separated from those pertaining to the coupled chemical reactions. The following kinetic cases have been treated in some detail: EC, simple ECE, catalytic, 1/2 regeneration scheme, and the moee general ECEC decay scheme. Single and double potential step and cyclic voltammetry methods have been treated theoretically via finite difference or analytical solutions and their potential utility for analyzing the pertinent rate constants is discussed.

Original language	English (US)
Pages (from-to)	153-158
Number of pages	6
Journal	Analytical Chemistry
Volume	44
Issue number	1
DOIs	https://doi.org/10.1021/ac60309a027
State	Published - Jan 1 1972

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.1021/ac60309a027

Fingerprint Dive into the research topics of 'Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer'. Together they form a unique fingerprint.

Cite this

@article{66afe49134c44a63984025f4fb665da1,

title = "Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer",

abstract = "A simple method is presented for analyzing the temperature dependence of pseudo first order chemical reaction(s) coupled to a heterogeneous charge transfer process. The temperature dependent factors associated with the mass transport and heterogeneous charge transfer processes have been specifically separated from those pertaining to the coupled chemical reactions. The following kinetic cases have been treated in some detail: EC, simple ECE, catalytic, 1/2 regeneration scheme, and the moee general ECEC decay scheme. Single and double potential step and cyclic voltammetry methods have been treated theoretically via finite difference or analytical solutions and their potential utility for analyzing the pertinent rate constants is discussed.",

author = "{Van Duyne}, {Richard P} and Reilley, {Charles N.}",

year = "1972",

month = jan,

day = "1",

doi = "10.1021/ac60309a027",

language = "English (US)",

volume = "44",

pages = "153--158",

journal = "Industrial And Engineering Chemistry Analytical Edition",

issn = "0003-2700",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer

AU - Van Duyne, Richard P

AU - Reilley, Charles N.

PY - 1972/1/1

Y1 - 1972/1/1

N2 - A simple method is presented for analyzing the temperature dependence of pseudo first order chemical reaction(s) coupled to a heterogeneous charge transfer process. The temperature dependent factors associated with the mass transport and heterogeneous charge transfer processes have been specifically separated from those pertaining to the coupled chemical reactions. The following kinetic cases have been treated in some detail: EC, simple ECE, catalytic, 1/2 regeneration scheme, and the moee general ECEC decay scheme. Single and double potential step and cyclic voltammetry methods have been treated theoretically via finite difference or analytical solutions and their potential utility for analyzing the pertinent rate constants is discussed.

AB - A simple method is presented for analyzing the temperature dependence of pseudo first order chemical reaction(s) coupled to a heterogeneous charge transfer process. The temperature dependent factors associated with the mass transport and heterogeneous charge transfer processes have been specifically separated from those pertaining to the coupled chemical reactions. The following kinetic cases have been treated in some detail: EC, simple ECE, catalytic, 1/2 regeneration scheme, and the moee general ECEC decay scheme. Single and double potential step and cyclic voltammetry methods have been treated theoretically via finite difference or analytical solutions and their potential utility for analyzing the pertinent rate constants is discussed.

UR - http://www.scopus.com/inward/record.url?scp=25044434234&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=25044434234&partnerID=8YFLogxK

U2 - 10.1021/ac60309a027

DO - 10.1021/ac60309a027

M3 - Article

AN - SCOPUS:25044434234

VL - 44

SP - 153

EP - 158

JO - Industrial And Engineering Chemistry Analytical Edition

JF - Industrial And Engineering Chemistry Analytical Edition

SN - 0003-2700

IS - 1

ER -

Low-Temperature Electrochemistry II. Evaluation of Rate Constants and Activation Parameters for Homogeneous Chemical Reactions Coupled to Charge Transfer

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this