Low-Valent Nickel Complexes of Substituted Diazenes

Steven D. Ittel, James A Ibers

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Substituted diazenes react with zerovalent nickel phosphine complexes to form Π complexes or to eliminate dinitrogen to form nickel(II) species. Possible alternative mechanisms for the photochromic behavior of an azobenzene Π complex are suggested. Several cyano- and alkyl-substituted diazenes have been shown to eliminate dinitrogen and oxidatively add to the Ni(0) complexes. Evidence is presented to suggest that oxidative addition takes place through a Π intermediate. A new complex of bis(p-methylbenzoyl)diazene exhibits a fluxional behavior between square-planar and tetrahedral coordination about the nickel atom.

Original languageEnglish (US)
Pages (from-to)1183-1189
Number of pages7
JournalInorganic chemistry
Volume14
Issue number5
DOIs
StatePublished - May 1 1975

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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