Macrobicyclic Polyethers as Second Sphere Ligands for Tetraammineplatinum(II)

David R. Alston, Alexandra M Z Slawin, J. Fraser Stoddart*, David J. Williams, Ryszard Zarzycki

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

A T‐arrangement of two benzene rings contributes—aside from H‐bridges—to the stabilization of a 2:1 adduct of the molecular receptor 2 with [Pt(NH3)4]2⊕ in the solid state (X‐ray structure analysis); in [D6]acetone only a 1:1 adduct is present (1H‐NMR). With the same cation, 1 forms only 1:1 adducts in solution and in the solid state. Thus, small changes in the ligands can drastically alter its bonding properties (1, R  H; 2, R  Me). (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)693-696
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume26
Issue number7
DOIs
StatePublished - Jul 1987

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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