Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes

David R. Alston, Alexandra M Z Slawin, J. Fraser Stoddart*, David J. Williams

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

23 Scopus citations

Abstract

Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis‐diammine complexes such as [Rh(cod)(NH3)2][PF6]. 1, X  OCH2CH2O, O‐o‐C6H4O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)821-823
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume23
Issue number10
DOIs
StatePublished - Jan 1 1984

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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