Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes

David R. Alston; Alexandra M Z Slawin; J. Fraser Stoddart; David J. Williams

doi:10.1002/anie.198408211

Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes

David R. Alston, Alexandra M Z Slawin, J. Fraser Stoddart^*, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis‐diammine complexes such as [Rh(cod)(NH₃)₂][PF₆]. 1, X  OCH₂CH₂O, O‐o‐C₆H₄O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges. (Figure Presented.)

Original language	English (US)
Pages (from-to)	821-823
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	23
Issue number	10
DOIs	https://doi.org/10.1002/anie.198408211
State	Published - Oct 1984

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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title = "Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes",

abstract = "Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis‐diammine complexes such as [Rh(cod)(NH3)2][PF6]. 1, X  OCH2CH2O, O‐o‐C6H4O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges. (Figure Presented.)",

author = "Alston, {David R.} and Slawin, {Alexandra M Z} and Stoddart, {J. Fraser} and Williams, {David J.}",

year = "1984",

month = oct,

doi = "10.1002/anie.198408211",

language = "English (US)",

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pages = "821--823",

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T1 - Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes

AU - Alston, David R.

AU - Slawin, Alexandra M Z

AU - Stoddart, J. Fraser

AU - Williams, David J.

PY - 1984/10

Y1 - 1984/10

N2 - Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis‐diammine complexes such as [Rh(cod)(NH3)2][PF6]. 1, X  OCH2CH2O, O‐o‐C6H4O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges. (Figure Presented.)

AB - Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis‐diammine complexes such as [Rh(cod)(NH3)2][PF6]. 1, X  OCH2CH2O, O‐o‐C6H4O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges. (Figure Presented.)

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M3 - Article

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JF - Angewandte Chemie - International Edition

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ER -

Macrobicyclic Polyethers as V‐Shaped Hosts for cis‐Diammine‐Transition Metal Complexes

Abstract

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