Macrocycle contraction reactions of 5,35: 14,19-diimino-7,12 : 21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21]pentaazacyclopentacosinato- dioxouranium(VI)

Tobin J. Marks; Djordje R. Stojakovic

doi:10.1039/C39750000028

Macrocycle contraction reactions of 5,35: 14,19-diimino-7,12 : 21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21]pentaazacyclopentacosinato- dioxouranium(VI)

Tobin J. Marks^*, Djordje R. Stojakovic

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Displacement of the uranyl ion from 5,35 : 14,19-diimino-7,12,21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21] pentaazacyclopentacosinatodioxouranium(VI) with a variety of metal ions is accompanied by ring contraction, yielding the corresponding metal phthalocyanine.

Original language	English (US)
Pages (from-to)	28-29
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39750000028
State	Published - 1975

Funding

. . . 600 650 700 750 800 850 900 950 1000 1050 1 /nm FIGURE.Spectrophotometric record of the reaction of SPcUO, with CuCI, in 200: 1 l-chloronaphthalene-DMF at 76°C;ob-served second-order rate constant = 0-26 1 mol-I sec-l. i~energy of SPcH, is not significantly different from that of PcH,* plus phthalonitrile. We thank the National Science Foundation and the Paint Research Institute for support, and Messrs. J. Krecisz and E. Fliesher for assistance. T.J.M. is a fellow of the A. P. Sloan Foundation. (Received, 15th October 1974;Corn. 1282.) V. W. Day, T. J. Marks, and W. A. Wachter, J. Amer. Chem. Soc., 1974, in the press. F. A. Moser and A. L. Thomas, ‘Phthalocyanine Compounds,’ Reinhold Publishing Corp., New York, 1963; A. B. P. Lever, Adv. Inorg. Chem. Radiochem., 1965, 7, 26. a F. Lux, Proceedings, Tenth Rare Earth Research Conference, Carefree, Arizona, May 1973, p. 871. (a) D. St. C. Black and E. Markham, Rev. Pure AppZ. Chem., 1965, 15, 109; (b) D. H. Busch, HeZv. Chim. Acta, Fax. Extraordin-arius, Alfred Werner Commemoration Volume, 1967; (c) N. F. Curtis, Co-ordination Chew. Rev., 1968,3, 3; (d) L. F. Lindoy and D. H. Busch, Prep. Inorg. React., 1971, 6, 1; (e) M. K. Friedel, B. T. Hoskins, R. L. Martin, and S. A. Mason, Chem. Comm., 1970, 400. 6 A. L. Allred and L. W.Busch, J. Amer. Chem. Soc., 1968,90, 3352. We thank Professor Allred for the use of this HMO program. I. Chen, J. Mol. Spectroscopy, 1967, 23, 131; J. Chem. Phys., 1969, 51, 3241.

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Molecular Medicine

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@article{786e824b6a6b4118a1029e30456a06cd,

title = "Macrocycle contraction reactions of 5,35: 14,19-diimino-7,12 : 21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21]pentaazacyclopentacosinato- dioxouranium(VI)",

abstract = "Displacement of the uranyl ion from 5,35 : 14,19-diimino-7,12,21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21] pentaazacyclopentacosinatodioxouranium(VI) with a variety of metal ions is accompanied by ring contraction, yielding the corresponding metal phthalocyanine.",

author = "Marks, {Tobin J.} and Stojakovic, {Djordje R.}",

note = "Funding Information: . . . 600 650 700 750 800 850 900 950 1000 1050 1 /nm FIGURE.Spectrophotometric record of the reaction of SPcUO, with CuCI, in 200: 1 l-chloronaphthalene-DMF at 76°C;ob-served second-order rate constant = 0-26 1 mol-I sec-l. i~energy of SPcH, is not significantly different from that of PcH,* plus phthalonitrile. We thank the National Science Foundation and the Paint Research Institute for support, and Messrs. J. Krecisz and E. Fliesher for assistance. T.J.M. is a fellow of the A. P. Sloan Foundation. (Received, 15th October 1974;Corn. 1282.) V. W. Day, T. J. Marks, and W. A. Wachter, J. Amer. Chem. Soc., 1974, in the press. F. A. Moser and A. L. Thomas, {\textquoteleft}Phthalocyanine Compounds,{\textquoteright} Reinhold Publishing Corp., New York, 1963; A. B. P. Lever, Adv. Inorg. Chem. Radiochem., 1965, 7, 26. a F. Lux, Proceedings, Tenth Rare Earth Research Conference, Carefree, Arizona, May 1973, p. 871. (a) D. St. C. Black and E. Markham, Rev. Pure AppZ. Chem., 1965, 15, 109; (b) D. H. Busch, HeZv. Chim. Acta, Fax. Extraordin-arius, Alfred Werner Commemoration Volume, 1967; (c) N. F. Curtis, Co-ordination Chew. Rev., 1968,3, 3; (d) L. F. Lindoy and D. H. Busch, Prep. Inorg. React., 1971, 6, 1; (e) M. K. Friedel, B. T. Hoskins, R. L. Martin, and S. A. Mason, Chem. Comm., 1970, 400. 6 A. L. Allred and L. W.Busch, J. Amer. Chem. Soc., 1968,90, 3352. We thank Professor Allred for the use of this HMO program. I. Chen, J. Mol. Spectroscopy, 1967, 23, 131; J. Chem. Phys., 1969, 51, 3241.",

year = "1975",

doi = "10.1039/C39750000028",

language = "English (US)",

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journal = "Journal of the Chemical Society, Chemical Communications",

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T2 - 14,19-diimino-7,12 : 21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21]pentaazacyclopentacosinato- dioxouranium(VI)

AU - Marks, Tobin J.

AU - Stojakovic, Djordje R.

N1 - Funding Information: . . . 600 650 700 750 800 850 900 950 1000 1050 1 /nm FIGURE.Spectrophotometric record of the reaction of SPcUO, with CuCI, in 200: 1 l-chloronaphthalene-DMF at 76°C;ob-served second-order rate constant = 0-26 1 mol-I sec-l. i~energy of SPcH, is not significantly different from that of PcH,* plus phthalonitrile. We thank the National Science Foundation and the Paint Research Institute for support, and Messrs. J. Krecisz and E. Fliesher for assistance. T.J.M. is a fellow of the A. P. Sloan Foundation. (Received, 15th October 1974;Corn. 1282.) V. W. Day, T. J. Marks, and W. A. Wachter, J. Amer. Chem. Soc., 1974, in the press. F. A. Moser and A. L. Thomas, ‘Phthalocyanine Compounds,’ Reinhold Publishing Corp., New York, 1963; A. B. P. Lever, Adv. Inorg. Chem. Radiochem., 1965, 7, 26. a F. Lux, Proceedings, Tenth Rare Earth Research Conference, Carefree, Arizona, May 1973, p. 871. (a) D. St. C. Black and E. Markham, Rev. Pure AppZ. Chem., 1965, 15, 109; (b) D. H. Busch, HeZv. Chim. Acta, Fax. Extraordin-arius, Alfred Werner Commemoration Volume, 1967; (c) N. F. Curtis, Co-ordination Chew. Rev., 1968,3, 3; (d) L. F. Lindoy and D. H. Busch, Prep. Inorg. React., 1971, 6, 1; (e) M. K. Friedel, B. T. Hoskins, R. L. Martin, and S. A. Mason, Chem. Comm., 1970, 400. 6 A. L. Allred and L. W.Busch, J. Amer. Chem. Soc., 1968,90, 3352. We thank Professor Allred for the use of this HMO program. I. Chen, J. Mol. Spectroscopy, 1967, 23, 131; J. Chem. Phys., 1969, 51, 3241.

PY - 1975

Y1 - 1975

N2 - Displacement of the uranyl ion from 5,35 : 14,19-diimino-7,12,21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21] pentaazacyclopentacosinatodioxouranium(VI) with a variety of metal ions is accompanied by ring contraction, yielding the corresponding metal phthalocyanine.

AB - Displacement of the uranyl ion from 5,35 : 14,19-diimino-7,12,21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21] pentaazacyclopentacosinatodioxouranium(VI) with a variety of metal ions is accompanied by ring contraction, yielding the corresponding metal phthalocyanine.

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M3 - Article

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 1

ER -

Macrocycle contraction reactions of 5,35: 14,19-diimino-7,12 : 21,26 : 28,33-trinitrilopentabenzo [c,h,m,r,w][1,6,11,16,21]pentaazacyclopentacosinato- dioxouranium(VI)

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