Abstract
A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen, and nitrogen heteroatoms is presented along with the single-crystal X-ray structures of the thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines capable of coordinating multiple metal ions.
Original language | English (US) |
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Pages (from-to) | 8175-8188 |
Number of pages | 14 |
Journal | Tetrahedron |
Volume | 51 |
Issue number | 30 |
DOIs | |
State | Published - Jul 24 1995 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry