Macrocyclic dithiomaleonitrile derivatives containing sulfur and nitrogen heteroatoms

Steven J. Lange*, John W. Sibert, Charlotte L. Stern, A. G M Barrett, Brian M. Hoffman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen, and nitrogen heteroatoms is presented along with the single-crystal X-ray structures of the thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines capable of coordinating multiple metal ions.

Original languageEnglish (US)
Pages (from-to)8175-8188
Number of pages14
JournalTetrahedron
Volume51
Issue number30
DOIs
StatePublished - Jul 24 1995

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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