TY - JOUR
T1 - Manganese(II) octauranium(IV) heptadecasulfide
AU - Oh, George N.
AU - Ibers, James A.
PY - 2011/9
Y1 - 2011/9
N2 - Single crystals of manganese(II) octauranium(IV) heptadecasulfide, MnU 8S 17, were grown from the reaction of the elements in a RbCl flux. MnU 8S 17 crystallizes in the space group C2/m in the CrU 8S 17 structure type. The asymmetric unit is composed of the following atoms with site symmetries shown: U1 (1), U2 (m), U3 (m), Mn1 (2/m), S1 (1), S2 (1); S3 (m), S4 (m), S5 (m), S6 (m) and S7 (2/m). The three U IV atoms are each coordinated by eight S atoms in a bicapped trigonal-prismatic arrangement. The Mn II atom is coordinated by six S atoms in a distorted octa-hedral arrangement.
AB - Single crystals of manganese(II) octauranium(IV) heptadecasulfide, MnU 8S 17, were grown from the reaction of the elements in a RbCl flux. MnU 8S 17 crystallizes in the space group C2/m in the CrU 8S 17 structure type. The asymmetric unit is composed of the following atoms with site symmetries shown: U1 (1), U2 (m), U3 (m), Mn1 (2/m), S1 (1), S2 (1); S3 (m), S4 (m), S5 (m), S6 (m) and S7 (2/m). The three U IV atoms are each coordinated by eight S atoms in a bicapped trigonal-prismatic arrangement. The Mn II atom is coordinated by six S atoms in a distorted octa-hedral arrangement.
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U2 - 10.1107/S1600536811030546
DO - 10.1107/S1600536811030546
M3 - Article
C2 - 22058832
AN - SCOPUS:80052683194
SN - 1600-5368
VL - 67
SP - i46
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 9
ER -