Manganese(II) octauranium(IV) heptadecasulfide

George N. Oh, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Single crystals of manganese(II) octauranium(IV) heptadecasulfide, MnU 8S 17, were grown from the reaction of the elements in a RbCl flux. MnU 8S 17 crystallizes in the space group C2/m in the CrU 8S 17 structure type. The asymmetric unit is composed of the following atoms with site symmetries shown: U1 (1), U2 (m), U3 (m), Mn1 (2/m), S1 (1), S2 (1); S3 (m), S4 (m), S5 (m), S6 (m) and S7 (2/m). The three U IV atoms are each coordinated by eight S atoms in a bicapped trigonal-prismatic arrangement. The Mn II atom is coordinated by six S atoms in a distorted octa-hedral arrangement.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume67
Issue number9
DOIs
StatePublished - Sep 1 2011

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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