Mathematical modeling of thiol-ene frontal polymerization

D. E. Devadoss, J. A. Pojman, V. A. Volpert*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations


Frontal polymerization is a method of manufacturing polymers via a self-propagating reaction wave. A mathematical model that describes thiol-ene frontal polymerization is presented and studied, both numerically and analytically. Spatio-temporal profiles of the temperature and concentrations of the reactants as well as the propagation velocity of the wave are determined. Conditions for existence of polymerization fronts are discussed.

Original languageEnglish (US)
Pages (from-to)1261-1275
Number of pages15
JournalChemical Engineering Science
Issue number4
StatePublished - Feb 2006


  • Frontal polymerization
  • Mathematical modeling
  • Reaction wave
  • Thiol-ene polymerization

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • Industrial and Manufacturing Engineering


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