Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites

Laura Dykes, Wesley Burghardt, Kosmas Kasimatis, John Torkelson

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Flow-induced changes in the orientation of dispersed clay particles is expected to have a significant effect on the properties of polymer/clay nanocomposite materials. Here we report studies of flow-induced orientation in dispersions of organically modified montmorillonite clay in polypropylene. The nanocomposite samples were prepared using two methods. Melt blending in a twin-screw extruder led to intercalated samples in which the layered structure of the clay remains intact. An additional step of solid-state shear pulverization leads to samples with a much higher degree of exfoliation of individual clay sheets. In situ x-ray scattering was used to probe particle orientation in steady shear using an annular cone and plate shear cell which provides information about particle orientation in the flow-gradient plane. The more highly exfoliated pulverized sample shows significantly lower orientation than the intercalated melt-blended sample. Both samples were also studied in extrusion-fed channel flows. In slit-channel geometries, the dominant shear rate direction is parallel to the x-ray beam, allowing information about orientation in the flow-vorticity plane to be acquired. In fact, little scattering was observed in these configurations, indicating the tendency of clay particles to 'lie down' in the shear flow. Superposition of extension via contractions or expansions in slit-channel flows did not reorient particles sufficiently to bring them 'into view' in these geometries. Extrusion experiments using a nominally two-dimensional slit flow, in which the beam passes along the vorticity direction, provided the means to obtain orientation data in these samples at higher shear rates than the annular cone and plate shear cell.

Original languageEnglish (US)
Title of host publication05AIChE
Subtitle of host publication2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings
Number of pages1
StatePublished - Dec 1 2005
Event05AIChE: 2005 AIChE Annual Meeting and Fall Showcase - Cincinnati, OH, United States
Duration: Oct 30 2005Nov 4 2005

Other

Other05AIChE: 2005 AIChE Annual Meeting and Fall Showcase
CountryUnited States
CityCincinnati, OH
Period10/30/0511/4/05

Fingerprint

Channel flow
Shear flow
Polypropylenes
Nanocomposites
Clay
Vorticity
Shear deformation
Extrusion
Cones
Scattering
X rays
Geometry
Extruders
Clay minerals
Dispersions
Polymers
Experiments

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Dykes, L., Burghardt, W., Kasimatis, K., & Torkelson, J. (2005). Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites. In 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings
Dykes, Laura ; Burghardt, Wesley ; Kasimatis, Kosmas ; Torkelson, John. / Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites. 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. 2005.
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Dykes, L, Burghardt, W, Kasimatis, K & Torkelson, J 2005, Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites. in 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Cincinnati, OH, United States, 10/30/05.

Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites. / Dykes, Laura; Burghardt, Wesley; Kasimatis, Kosmas; Torkelson, John.

05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. 2005.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Dykes L, Burghardt W, Kasimatis K, Torkelson J. Measurements of particle orientation in simple shear and channel flows of polypropylene/clay nanocomposites. In 05AIChE: 2005 AIChE Annual Meeting and Fall Showcase, Conference Proceedings. 2005