Mechanical shuttling of linear motor-molecules in condensed phases on solid substrates

Tony Jun Huang*, Hsian Rong Tseng, Lin Sha, Weixing Lu, Branden Brough, Amar H. Flood, Bi Dan Yu, Paul C. Celestre, Jane P. Chang, J. Fraser Stoddart, Chih Ming Ho

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

112 Scopus citations

Abstract

From analyses of pressure-area isotherms and X-ray photoelectron spectra, we have demonstrated that redox-controllable molecular shuttles, in the shape of amphiphilic, bistable rotaxanes, are mechanically switchable in closely packed Langmuir films with chemical reagents. Additionally, mechanical switching has been proven to occur in closely packed Langmuir-Blodgett bilayers while mounted on solid substrates. The results not only constitute a proof of principle but they also provide the impetus to develop solid-state nanoelectromechanical systems that have the potential to reach up to the mesoscale.

Original languageEnglish (US)
Pages (from-to)2065-2071
Number of pages7
JournalNano letters
Volume4
Issue number11
DOIs
StatePublished - Nov 2004

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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