Mechanism of Nitrogenase H2 Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects

Nimesh Khadka, Ross D. Milton, Sudipta Shaw, Dmitriy Lukoyanov, Dennis R. Dean, Shelley D. Minteer, Simone Raugei, Brian M. Hoffman*, Lance C. Seefeldt

*Corresponding author for this work

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Biochemistry, Genetics and Molecular Biology

Pharmacology, Toxicology and Pharmaceutical Science