Abstract
A typical configuration of an equilibrium 2D system of 2500 Lennard-Jones particles at melting is found to be a mosaic of crystallites and amorphous clusters. This mosaic significantly changed at times around the period τ of local vibrations, while most particles retain their nearest neighbors for times much longer than τ. In a system of 2500 particles, we found no phase separation for length scales larger than that of a crystallite. With decreasing density, the number of small amorphous clusters increased, and proliferation and percolation of amorphous matter separated the crystalline-ordered parts so that correlations between local order orientations of remote crystallites disappeared. We suggest that the mosaic is a manifestation of diminished stability of the crystalline structure resulting from competition between attraction and repulsion forces.
Original language | English (US) |
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Pages (from-to) | 20749-20755 |
Number of pages | 7 |
Journal | Journal of Physical Chemistry C |
Volume | 114 |
Issue number | 48 |
DOIs | |
State | Published - Dec 9 2010 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- General Energy
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films