Metal Carbonyl Complexes of Sapphyrins

Anthony K. Burrell; Jonathan L. Sessler; Michael J. Cyr; Ellen McGhee; James A. Ibers

doi:10.1002/anie.199100911

Metal Carbonyl Complexes of Sapphyrins

Anthony K. Burrell, Jonathan L. Sessler^*, Michael J. Cyr, Ellen McGhee, James A. Ibers

^*Corresponding author for this work

Chemistry

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Abstract

Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)₂}₂] and/or [IrCl(CO)₂(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)₂] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cyclohexenes. (Figure Presented.)

Original language	English (US)
Pages (from-to)	91-93
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	30
Issue number	1
DOIs	https://doi.org/10.1002/anie.199100911
State	Published - Jan 1991

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "Metal Carbonyl Complexes of Sapphyrins",

abstract = "Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)2}2] and/or [IrCl(CO)2(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)2] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cyclohexenes. (Figure Presented.)",

author = "Burrell, {Anthony K.} and Sessler, {Jonathan L.} and Cyr, {Michael J.} and Ellen McGhee and Ibers, {James A.}",

year = "1991",

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language = "English (US)",

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T1 - Metal Carbonyl Complexes of Sapphyrins

AU - Burrell, Anthony K.

AU - Sessler, Jonathan L.

AU - Cyr, Michael J.

AU - McGhee, Ellen

AU - Ibers, James A.

PY - 1991/1

Y1 - 1991/1

N2 - Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)2}2] and/or [IrCl(CO)2(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)2] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cyclohexenes. (Figure Presented.)

AB - Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)2}2] and/or [IrCl(CO)2(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)2] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cyclohexenes. (Figure Presented.)

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Metal Carbonyl Complexes of Sapphyrins

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