Metal-Organic Frameworks against Toxic Chemicals

Timur Islamoglu; Zhijie Chen; Megan C. Wasson; Cassandra T. Buru; Kent O. Kirlikovali; Unjila Afrin; Mohammad Rasel Mian; Omar K. Farha

doi:10.1021/acs.chemrev.9b00828

Metal-Organic Frameworks against Toxic Chemicals

Timur Islamoglu, Zhijie Chen, Megan C. Wasson, Cassandra T. Buru, Kent O. Kirlikovali, Unjila Afrin, Mohammad Rasel Mian, Omar K. Farha^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article

3 Scopus citations

Abstract

Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H₂S, NH₃, SO₂, CO, NO₂, and NO.

Original language	English (US)
Journal	Chemical Reviews
DOIs	https://doi.org/10.1021/acs.chemrev.9b00828
State	Accepted/In press - Jan 1 2020

ASJC Scopus subject areas

Chemistry(all)

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Islamoglu, T., Chen, Z., Wasson, M. C., Buru, C. T., Kirlikovali, K. O., Afrin, U., Mian, M. R., & Farha, O. K. (Accepted/In press). Metal-Organic Frameworks against Toxic Chemicals. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.9b00828

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abstract = "Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.",

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AU - Chen, Zhijie

AU - Wasson, Megan C.

AU - Buru, Cassandra T.

AU - Kirlikovali, Kent O.

AU - Afrin, Unjila

AU - Mian, Mohammad Rasel

AU - Farha, Omar K.

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