TY - JOUR
T1 - Metal-Organic Frameworks against Toxic Chemicals
AU - Islamoglu, Timur
AU - Chen, Zhijie
AU - Wasson, Megan C.
AU - Buru, Cassandra T.
AU - Kirlikovali, Kent O.
AU - Afrin, Unjila
AU - Mian, Mohammad Rasel
AU - Farha, Omar K.
N1 - Funding Information:
O.K.F. gratefully acknowledges support from the Defense Threat Reduction Agency (HDTRA1-18-1-0003, HDTRA1-19-1-0010, and HDTRA1-19-1-0007) and the U.S. Department of Energy (DOE) Office of Science, Basic Energy Sciences Program (Grant No. DE-FG02-08ER15967). M.C.W. is supported by the NSF Graduate Research Fellowship under Grant No. DGE-1842165. K.O.K. gratefully acknowledges support from the IIN Postdoctoral Fellowship and the Northwestern University International Institute for Nanotechnology.
Funding Information:
O.K.F. gratefully acknowledges support from the Defense Threat Reduction Agency (HDTRA1-18-1-0003, HDTRA1-19-1-0010 and HDTRA1-19-1-0007) and the U.S. Department of Energy (DOE) Office of Science, Basic Energy Sciences Program (Grant No. DE-FG02-08ER15967). M.C.W. is supported by the NSF Graduate Research Fellowship under Grant No. DGE-1842165. K.O.K. gratefully acknowledges support from the IIN Postdoctoral Fellowship and the Northwestern University International Institute for Nanotechnology.
PY - 2020/8/26
Y1 - 2020/8/26
N2 - Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.
AB - Materials capable of the safe and efficient capture or degradation of toxic chemicals, including chemical warfare agents (CWAs) and toxic industrial chemicals (TICs), are critically important in the modern age due to continuous threats of these chemicals to human life, both directly and indirectly. Metal-organic frameworks (MOFs), atomically precise hybrid materials that are synthesized via the self-assembly of metal cations or clusters and organic linkers, offer a unique solid adsorbent design platform due to their great synthetic versatility. This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents (organophosphorus nerve agents, blistering agents, and their simulants) and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.
UR - http://www.scopus.com/inward/record.url?scp=85082765853&partnerID=8YFLogxK
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U2 - 10.1021/acs.chemrev.9b00828
DO - 10.1021/acs.chemrev.9b00828
M3 - Review article
C2 - 32207607
AN - SCOPUS:85082765853
VL - 120
SP - 8130
EP - 8160
JO - Chemical Reviews
JF - Chemical Reviews
SN - 0009-2665
IS - 16
ER -