Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

Birinchi K. Das; Mercouri G. Kanatzidis

doi:10.1016/S0277-5387(97)00018-1

Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

Birinchi K. Das, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The tellurido ruthenium carbonyl cluster compounds (Ph₄P)₂[Ru₄Te₂(CO)₁₀] (1) and (Ph₂P)₂[Ru₅ Te(CO)₁₄] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru₃(CO)₁₂, Na₂Te₂ and Ph₄PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.

Original language	English (US)
Pages (from-to)	3061-3066
Number of pages	6
Journal	Polyhedron
Volume	16
Issue number	17
DOIs	https://doi.org/10.1016/S0277-5387(97)00018-1
State	Published - 1997

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{af25d7c5aad94d009b2245894e92d513,

title = "Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters",

abstract = "The tellurido ruthenium carbonyl cluster compounds (Ph4P)2[Ru4Te2(CO)10] (1) and (Ph2P)2[Ru5 Te(CO)14] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru3(CO)12, Na2Te2 and Ph4PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.",

author = "Das, {Birinchi K.} and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Acknowledgements-Financial support from the Donors of the Petroleum Research Fund administered by the American Chemical Society is gratefully acknowledged. MGK was a Camille and Henry Dreyfus Teacher Scholar (1993-1998).",

year = "1997",

doi = "10.1016/S0277-5387(97)00018-1",

language = "English (US)",

volume = "16",

pages = "3061--3066",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "17",

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TY - JOUR

T1 - Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

AU - Das, Birinchi K.

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: Acknowledgements-Financial support from the Donors of the Petroleum Research Fund administered by the American Chemical Society is gratefully acknowledged. MGK was a Camille and Henry Dreyfus Teacher Scholar (1993-1998).

PY - 1997

Y1 - 1997

N2 - The tellurido ruthenium carbonyl cluster compounds (Ph4P)2[Ru4Te2(CO)10] (1) and (Ph2P)2[Ru5 Te(CO)14] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru3(CO)12, Na2Te2 and Ph4PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.

AB - The tellurido ruthenium carbonyl cluster compounds (Ph4P)2[Ru4Te2(CO)10] (1) and (Ph2P)2[Ru5 Te(CO)14] (2) have been prepared by methanothermal reactions at 80°C using a reaction mixture of Ru3(CO)12, Na2Te2 and Ph4PBr in appropriate molar ratios. Both compounds have pseudo-octahedral cores formed by ruthenium and tellurium atoms.

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U2 - 10.1016/S0277-5387(97)00018-1

DO - 10.1016/S0277-5387(97)00018-1

M3 - Article

AN - SCOPUS:0007445545

SN - 0277-5387

VL - 16

SP - 3061

EP - 3066

JO - Polyhedron

JF - Polyhedron

IS - 17

ER -

Methanothermal synthesis of polynuclear ruthenium telluride carbonyl clusters

Abstract

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