Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System

Jin‐Ha ‐H Hwang; Thomas O. Mason; Vinayak P. Dravid

doi:10.1111/j.1151-2916.1994.tb09748.x

Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi₂O₃ System

Jin‐Ha ‐H Hwang^*, Thomas O. Mason, Vinayak P. Dravid

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

ZnO solidus and liquidus boundaries in the ZnO‐Bi₂O₃ system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi₂O₃ solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

Original language	English (US)
Pages (from-to)	1499-1504
Number of pages	6
Journal	Journal of the American Ceramic Society
Volume	77
Issue number	6
DOIs	https://doi.org/10.1111/j.1151-2916.1994.tb09748.x
State	Published - Jan 1 1994

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

Access to Document

10.1111/j.1151-2916.1994.tb09748.x

Cite this

@article{9e4a1a3e3a7041dd98162d314953ce6d,

title = "Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System",

abstract = "ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.",

author = "Hwang, {Jin‐Ha ‐H} and Mason, {Thomas O.} and Dravid, {Vinayak P.}",

year = "1994",

month = jan,

day = "1",

doi = "10.1111/j.1151-2916.1994.tb09748.x",

language = "English (US)",

volume = "77",

pages = "1499--1504",

journal = "Journal of the American Ceramic Society",

issn = "0002-7820",

publisher = "Wiley-Blackwell",

number = "6",

}

TY - JOUR

T1 - Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System

AU - Hwang, Jin‐Ha ‐H

AU - Mason, Thomas O.

AU - Dravid, Vinayak P.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

AB - ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

UR - http://www.scopus.com/inward/record.url?scp=0028459805&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0028459805&partnerID=8YFLogxK

U2 - 10.1111/j.1151-2916.1994.tb09748.x

DO - 10.1111/j.1151-2916.1994.tb09748.x

M3 - Article

AN - SCOPUS:0028459805

VL - 77

SP - 1499

EP - 1504

JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

SN - 0002-7820

IS - 6

ER -

Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi₂O₃ System

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this