Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System

Jin‐Ha ‐H Hwang; Thomas O. Mason; Vinayak P. Dravid

doi:10.1111/j.1151-2916.1994.tb09748.x

Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi₂O₃ System

Jin‐Ha ‐H Hwang^*, Thomas O. Mason, Vinayak P. Dravid

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

ZnO solidus and liquidus boundaries in the ZnO‐Bi₂O₃ system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi₂O₃ solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

Original language	English (US)
Pages (from-to)	1499-1504
Number of pages	6
Journal	Journal of the American Ceramic Society
Volume	77
Issue number	6
DOIs	https://doi.org/10.1111/j.1151-2916.1994.tb09748.x
State	Published - Jun 1994

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

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10.1111/j.1151-2916.1994.tb09748.x

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title = "Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System",

abstract = "ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol\%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.",

author = "Hwang, \{Jin‐Ha ‐H\} and Mason, \{Thomas O.\} and Dravid, \{Vinayak P.\}",

year = "1994",

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doi = "10.1111/j.1151-2916.1994.tb09748.x",

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T1 - Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi2O3 System

AU - Hwang, Jin‐Ha ‐H

AU - Mason, Thomas O.

AU - Dravid, Vinayak P.

PY - 1994/6

Y1 - 1994/6

N2 - ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

AB - ZnO solidus and liquidus boundaries in the ZnO‐Bi2O3 system were investigated via analytical electron microscopy (AEM), electron probe microanalysis (EPMA), and secondary ion mass spectrometry (SIMS). The Bi2O3 solubility is highest—0.24 ± 0.04 mol%—at the eutectic temperature of 740°C and decreases rapidly with increasing temperature. Detection limits and quantification procedures of X‐ray microanalysis (AEM, EPMA) and ion microanalysis (SIMS) are discussed with respect to the determination of phase diagrams involving low solubility phases.

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JF - Journal of the American Ceramic Society

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Microanalytical Determination of ZnO Solidus and Liquidus Boundaries in the ZnO‐Bi₂O₃ System

Abstract

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