Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

Bao Qing Ma; Karen L. Mulfort; Joseph T. Hupp

doi:10.1021/ic050452i

Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

Bao Qing Ma, Karen L. Mulfort, Joseph T. Hupp^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

442 Scopus citations

Abstract

The reaction of Zn(NO₃)₂·6H₂O, various dicarboxylic acids, and either 4,4′-bipyridine or N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

Original language	English (US)
Pages (from-to)	4912-4914
Number of pages	3
Journal	Inorganic chemistry
Volume	44
Issue number	14
DOIs	https://doi.org/10.1021/ic050452i
State	Published - Jul 11 2005

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic050452i

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title = "Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions",

abstract = "The reaction of Zn(NO3)2·6H2O, various dicarboxylic acids, and either 4,4′-bipyridine or N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.",

author = "Ma, {Bao Qing} and Mulfort, {Karen L.} and Hupp, {Joseph T.}",

year = "2005",

month = jul,

day = "11",

doi = "10.1021/ic050452i",

language = "English (US)",

volume = "44",

pages = "4912--4914",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

AU - Ma, Bao Qing

AU - Mulfort, Karen L.

AU - Hupp, Joseph T.

PY - 2005/7/11

Y1 - 2005/7/11

N2 - The reaction of Zn(NO3)2·6H2O, various dicarboxylic acids, and either 4,4′-bipyridine or N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

AB - The reaction of Zn(NO3)2·6H2O, various dicarboxylic acids, and either 4,4′-bipyridine or N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand, open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in the third. Despite 2-fold interpenetration, the compounds contain channels of molecular dimensions and several are permanently microporous, displaying high internal surface areas.

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JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 14

ER -

Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

Abstract

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CCDC 280539: Experimental Crystal Structure Determination

CCDC 280537: Experimental Crystal Structure Determination

CCDC 280540: Experimental Crystal Structure Determination

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Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 280539: Experimental Crystal Structure Determination

CCDC 280537: Experimental Crystal Structure Determination

CCDC 280540: Experimental Crystal Structure Determination

Cite this