Abstract
The effects of micro-additions of boron and zirconium on grain-boundary (GB) structure and strength in polycrystalline γ(f.c.c.) plus γ'(L12) strengthened Co-9.5Al-7.5W-X at% alloys (X=0-Ternary, 0.05B, 0.01B, 0.05Zr, and 0.005B-0.05Zr at%) are studied. Creep tests performed at 850 °C demonstrate that GB strength and cohesion limit the creep resistance and ductility of the ternary B- and Zr-free alloy due to intergranular fracture. Alloys with 0.05B and 0.005B-0.05Zr both exhibit improved creep strength due to enhanced GB cohesion, compared to the baseline ternary Co-9.5Al-7.5W alloy, but alloys containing 0.01B or 0.05Zr additions display no benefit. Atom-probe tomography (APT) is utilized to measure GB segregation, where B and Zr are demonstrated to segregate at GBs. A Gibbsian interfacial excess of 5.57±1.04 atoms nm−2 was found for B at a GB in the 0.01B alloy and 2.88±0.81 and 2.40±0.84 atoms nm−2 for B and Zr, respectively, for the 0.005B-0.05Zr alloy. The GBs in the highest B-containing (0.05B) alloy exhibit micrometer-sized boride precipitates with adjacent precipitate denuded-zones (PDZs), whereas secondary precipitation at the GBs is absent in the other four alloys. The 0.05B alloy has the smallest room temperature yield strength, by 6%, which is attributed to the PDZs, but it exhibits the largest increase in creep strength (with an ~2.5 order of magnitude decrease in the minimum strain rate for a given stress at 850 °C) over the baseline Co-9.5Al-7.5W alloy.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 260-269 |
| Number of pages | 10 |
| Journal | Materials Science and Engineering A |
| Volume | 682 |
| DOIs | |
| State | Published - Jan 13 2017 |
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Keywords
- Atom-probe tomography (APT)
- Cobalt-base superalloys
- Creep
- Gamma prime
- Grain boundaries
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
Cite this
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Microstructural and creep properties of boron- and zirconium-containing cobalt-based superalloys. / Bocchini, Peter J.; Sudbrack, Chantal K.; Noebe, Ronald D.; Dunand, David C.; Seidman, David N.
In: Materials Science and Engineering A, Vol. 682, 13.01.2017, p. 260-269.Research output: Contribution to journal › Article
TY - JOUR
T1 - Microstructural and creep properties of boron- and zirconium-containing cobalt-based superalloys
AU - Bocchini, Peter J.
AU - Sudbrack, Chantal K.
AU - Noebe, Ronald D.
AU - Dunand, David C.
AU - Seidman, David N.
PY - 2017/1/13
Y1 - 2017/1/13
N2 - The effects of micro-additions of boron and zirconium on grain-boundary (GB) structure and strength in polycrystalline γ(f.c.c.) plus γ'(L12) strengthened Co-9.5Al-7.5W-X at% alloys (X=0-Ternary, 0.05B, 0.01B, 0.05Zr, and 0.005B-0.05Zr at%) are studied. Creep tests performed at 850 °C demonstrate that GB strength and cohesion limit the creep resistance and ductility of the ternary B- and Zr-free alloy due to intergranular fracture. Alloys with 0.05B and 0.005B-0.05Zr both exhibit improved creep strength due to enhanced GB cohesion, compared to the baseline ternary Co-9.5Al-7.5W alloy, but alloys containing 0.01B or 0.05Zr additions display no benefit. Atom-probe tomography (APT) is utilized to measure GB segregation, where B and Zr are demonstrated to segregate at GBs. A Gibbsian interfacial excess of 5.57±1.04 atoms nm−2 was found for B at a GB in the 0.01B alloy and 2.88±0.81 and 2.40±0.84 atoms nm−2 for B and Zr, respectively, for the 0.005B-0.05Zr alloy. The GBs in the highest B-containing (0.05B) alloy exhibit micrometer-sized boride precipitates with adjacent precipitate denuded-zones (PDZs), whereas secondary precipitation at the GBs is absent in the other four alloys. The 0.05B alloy has the smallest room temperature yield strength, by 6%, which is attributed to the PDZs, but it exhibits the largest increase in creep strength (with an ~2.5 order of magnitude decrease in the minimum strain rate for a given stress at 850 °C) over the baseline Co-9.5Al-7.5W alloy.
AB - The effects of micro-additions of boron and zirconium on grain-boundary (GB) structure and strength in polycrystalline γ(f.c.c.) plus γ'(L12) strengthened Co-9.5Al-7.5W-X at% alloys (X=0-Ternary, 0.05B, 0.01B, 0.05Zr, and 0.005B-0.05Zr at%) are studied. Creep tests performed at 850 °C demonstrate that GB strength and cohesion limit the creep resistance and ductility of the ternary B- and Zr-free alloy due to intergranular fracture. Alloys with 0.05B and 0.005B-0.05Zr both exhibit improved creep strength due to enhanced GB cohesion, compared to the baseline ternary Co-9.5Al-7.5W alloy, but alloys containing 0.01B or 0.05Zr additions display no benefit. Atom-probe tomography (APT) is utilized to measure GB segregation, where B and Zr are demonstrated to segregate at GBs. A Gibbsian interfacial excess of 5.57±1.04 atoms nm−2 was found for B at a GB in the 0.01B alloy and 2.88±0.81 and 2.40±0.84 atoms nm−2 for B and Zr, respectively, for the 0.005B-0.05Zr alloy. The GBs in the highest B-containing (0.05B) alloy exhibit micrometer-sized boride precipitates with adjacent precipitate denuded-zones (PDZs), whereas secondary precipitation at the GBs is absent in the other four alloys. The 0.05B alloy has the smallest room temperature yield strength, by 6%, which is attributed to the PDZs, but it exhibits the largest increase in creep strength (with an ~2.5 order of magnitude decrease in the minimum strain rate for a given stress at 850 °C) over the baseline Co-9.5Al-7.5W alloy.
KW - Atom-probe tomography (APT)
KW - Cobalt-base superalloys
KW - Creep
KW - Gamma prime
KW - Grain boundaries
UR - http://www.scopus.com/inward/record.url?scp=84998881916&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84998881916&partnerID=8YFLogxK
U2 - 10.1016/j.msea.2016.10.124
DO - 10.1016/j.msea.2016.10.124
M3 - Article
AN - SCOPUS:84998881916
VL - 682
SP - 260
EP - 269
JO - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing
JF - Materials Science & Engineering A: Structural Materials: Properties, Microstructure and Processing
SN - 0921-5093
ER -