Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

Sven Schneider; John A.S. Roberts; Michael R. Salata; Tobin J. Marks

doi:10.1002/anie.200503691

Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu₂S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

Sven Schneider^*, John A.S. Roberts, Michael R. Salata, Tobin J. Marks

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

(Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu₂S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

Original language	English (US)
Pages (from-to)	1733-1736
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	11
DOIs	https://doi.org/10.1002/anie.200503691
State	Published - Mar 3 2006

Keywords

Cleavage reactions
Cluster compounds
Copper
S ligands

ASJC Scopus subject areas

Chemistry(all)
Catalysis

Access to Document

10.1002/anie.200503691

Cite this

@article{00a0e3f1d7204a8fadf70fe89741085b,

title = "Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks",

abstract = "(Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).",

keywords = "Cleavage reactions, Cluster compounds, Copper, S ligands",

author = "Sven Schneider and Roberts, {John A.S.} and Salata, {Michael R.} and Marks, {Tobin J.}",

year = "2006",

month = mar,

day = "3",

doi = "10.1002/anie.200503691",

language = "English (US)",

volume = "45",

pages = "1733--1736",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "11",

}

Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu₂S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks. / Schneider, Sven; Roberts, John A.S.; Salata, Michael R. et al.
In: Angewandte Chemie - International Edition, Vol. 45, No. 11, 03.03.2006, p. 1733-1736.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Mixed diketonate thiolate copper(I) precursors for materials synthesis

T2 - Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

AU - Schneider, Sven

AU - Roberts, John A.S.

AU - Salata, Michael R.

AU - Marks, Tobin J.

PY - 2006/3/3

Y1 - 2006/3/3

N2 - (Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

AB - (Chemical Equation Presented) Scission precision: The combination of Lewis acidic and Lewis basic building blocks in copper(I) thiolate clusters enables control of the thermal decomposition pathway in the design of new molecular precursors for Cu2S formation. After C-S bond scission, large clusters with cuprous sulfide cores are isolated as intermediates and are structurally characterized (see scheme; hfa = hexafluoroacetylacetonate).

KW - Cleavage reactions

KW - Cluster compounds

KW - Copper

KW - S ligands

UR - http://www.scopus.com/inward/record.url?scp=33746310590&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33746310590&partnerID=8YFLogxK

U2 - 10.1002/anie.200503691

DO - 10.1002/anie.200503691

M3 - Article

C2 - 16470752

AN - SCOPUS:33746310590

SN - 1433-7851

VL - 45

SP - 1733

EP - 1736

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu₂S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

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CCDC 286632: Experimental Crystal Structure Determination

CCDC 286630: Experimental Crystal Structure Determination

CCDC 286631: Experimental Crystal Structure Determination

Cite this

Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu2S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 286632: Experimental Crystal Structure Determination

CCDC 286630: Experimental Crystal Structure Determination

CCDC 286631: Experimental Crystal Structure Determination

Cite this

Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu₂S-forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks