Molecular Generality of Surface-Enhanced Raman Spectroscopy: Application to the Study of Surface Resonance Raman-Enhanced Complexes of Iron (II) with 1,10-Phenanthroline on Silver and Iron

R. P. Van Duyne, M. Janik-Czachor

Research output: Contribution to journalArticlepeer-review

8 Scopus citations

Abstract

RR and SERR spectra of adsorbed complexes of 1,10 phenantroline with Fe(II) (viz., Fe(phen)3+2) on silver from highly dilute solution (viz., 5 × 10−6M) are presented. The first attempt to combine SERS and RRS in order to investigate the surface spectra of Fe(phen)3+2 on an iron substrate is also reported. The results are encouraging with regard to possible application of SERS and RRS to studies of wet metallic corrosion, in situ.

Original languageEnglish (US)
Pages (from-to)2320-2323
Number of pages4
JournalJournal of the Electrochemical Society
Volume130
Issue number12
DOIs
StatePublished - Dec 1983

Keywords

  • complex
  • iron
  • phenanthroline
  • raman spectroscopy

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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