Molecular orientation of a liquid-crystalline polymer solution in mixed shear-extensional flows

Bruce D. Bedford, Wesley Roth Burghardt*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

41 Scopus citations

Abstract

A lyotropic solution of hydroxypropylcellulose in m-cresol has been studied in a nonhomogeneous shear (plane Poiseuille) flow, and in a set of flows with mixed shear and extension (slit contractions). The average molecular orientation is measured using flow birefringence, while laser-Doppler velocimetry is used to characterize extensional kinematics in the slit-contraction flows. IN slit flow, we observe very similar behavior to recently publishe observations in another model lyotropic, PBG in m-cresol [B. D. Bedford and W. R. Burghardt, J. Rheol. 38, 1657 (1994)]. Steady flow at low rates gives way to an instability characterized by large scale structural heterogeneities and time-dependent birefringence at higher rates. Throughout the entire flow rate range, however, average birefringence mearused in slit flow may be quantitatively predicted from simple shear flow data, assuming that the locally averaged rheological and structural properites in the slit flow are equivalent to those occurring in simple shear flow at identical stress levels. In slit-contraction flows we have observed substantial enhancements in molecular orientation in the vicinity of the contraction, resulting from extensinal velocity gradients. Orientation is studied in a variety of geometries in which contraction ratio and shape are varied to change the relative balance of shear and extension. We attribute the increased alignment to a transition from tumbling to flow-aligning dynamics due to the presence of extension in the contraction region.

Original languageEnglish (US)
Pages (from-to)235-257
Number of pages23
JournalJournal of Rheology
Volume40
Issue number2
DOIs
StatePublished - Jan 1 1996

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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