Molecular rectification through electric field induced conformational changes

Alessandro Troisi*, Mark A. Ratner

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

90 Scopus citations

Abstract

A new approach for the design of a molecular rectifier is proposed. Using a simple model, we have shown that conformational changes induced by the electric field may lead to a rectifying junction. The simplest possible rectifier of this kind presents two almost isoenergetic conformations, with different conductances and dipole moments. A simple equation allows for the estimation of the range of molecular parameters and temperatures that lead to an effective rectification. Examples show that rectification based on this mechanism is also possible at room temperature.

Original languageEnglish (US)
Pages (from-to)14528-14529
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number49
DOIs
StatePublished - Dec 11 2002

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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