Molecular structure of an unusual organoactinide hydride complex determined solely by neutron diffraction

Robert W. Broach; Arthur J. Schultz; Jack M. Williams; George M. Brown; Juan M. Manriquez; Paul J. Fagan; Tobin J. Marks

doi:10.1126/science.203.4376.172

Molecular structure of an unusual organoactinide hydride complex determined solely by neutron diffraction

Robert W. Broach^*, Arthur J. Schultz, Jack M. Williams, George M. Brown, Juan M. Manriquez, Paul J. Fagan, Tobin J. Marks

^*Corresponding author for this work

Chemistry

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Abstract

The structure of an unusual organometallic complex, {Th[(CH ₃)₅C₅]₂ H(μ-H)}₂ · C₆H₅CH₃, has been determined from neutron diffraction data, using only the direct-methods program MULTAN. Besides providing accurate metrical information on the first organometallic actinide hydride complex, these results have general and far-reaching implications concerning the complexity and size of crystal structures that can be elucidated solely on the basis of neutron diffraction data.

Original language	English (US)
Pages (from-to)	172-174
Number of pages	3
Journal	Science
Volume	203
Issue number	4376
DOIs	https://doi.org/10.1126/science.203.4376.172
State	Published - 1979

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abstract = "The structure of an unusual organometallic complex, {Th[(CH 3)5C5]2 H(μ-H)}2 · C6H5CH3, has been determined from neutron diffraction data, using only the direct-methods program MULTAN. Besides providing accurate metrical information on the first organometallic actinide hydride complex, these results have general and far-reaching implications concerning the complexity and size of crystal structures that can be elucidated solely on the basis of neutron diffraction data.",

author = "Broach, {Robert W.} and Schultz, {Arthur J.} and Williams, {Jack M.} and Brown, {George M.} and Manriquez, {Juan M.} and Fagan, {Paul J.} and Marks, {Tobin J.}",

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doi = "10.1126/science.203.4376.172",

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AU - Broach, Robert W.

AU - Schultz, Arthur J.

AU - Williams, Jack M.

AU - Brown, George M.

AU - Manriquez, Juan M.

AU - Fagan, Paul J.

AU - Marks, Tobin J.

PY - 1979

Y1 - 1979

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AB - The structure of an unusual organometallic complex, {Th[(CH 3)5C5]2 H(μ-H)}2 · C6H5CH3, has been determined from neutron diffraction data, using only the direct-methods program MULTAN. Besides providing accurate metrical information on the first organometallic actinide hydride complex, these results have general and far-reaching implications concerning the complexity and size of crystal structures that can be elucidated solely on the basis of neutron diffraction data.

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JO - Science

JF - Science

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Molecular structure of an unusual organoactinide hydride complex determined solely by neutron diffraction

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