Monofunctionalized pillar[5]arene as a host for alkanediamines

Nathan L. Strutt; Ross S. Forgan; Jason M. Spruell; Youssry Y. Botros; J. Fraser Stoddart

doi:10.1021/ja111418j

Monofunctionalized pillar[5]arene as a host for alkanediamines

Nathan L. Strutt, Ross S. Forgan, Jason M. Spruell, Youssry Y. Botros, J. Fraser Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

469 Scopus citations

Abstract

Alkanediamines serve as neutral guests for the recently discovered host pillar[5]arene. The proposed [2]pseudorotaxane nature of the superstructure of the 1:1 host-guest complexes is supported by the template-directed synthesis of a related [2]rotaxane. A synthetic route to monofunctional pillar[5]arenes has also been developed, allowing for the creation of a fluorescent sensor for alkylamine binding. The precursors to this host could act as starting points for a large library of monofunctional pillar[5]arene macrocycles.

Original language	English (US)
Pages (from-to)	5668-5671
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	15
DOIs	https://doi.org/10.1021/ja111418j
State	Published - Apr 20 2011

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja111418j

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abstract = "Alkanediamines serve as neutral guests for the recently discovered host pillar[5]arene. The proposed [2]pseudorotaxane nature of the superstructure of the 1:1 host-guest complexes is supported by the template-directed synthesis of a related [2]rotaxane. A synthetic route to monofunctional pillar[5]arenes has also been developed, allowing for the creation of a fluorescent sensor for alkylamine binding. The precursors to this host could act as starting points for a large library of monofunctional pillar[5]arene macrocycles.",

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AU - Stoddart, J. Fraser

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Monofunctionalized pillar[5]arene as a host for alkanediamines

Abstract

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