Multiplet splitting of core-electron binding energies in transition-metal ions

C. S. Fadley; D. A. Shirley; A. J. Freeman; P. S. Bagus; J. V. Mallow

doi:10.1103/PhysRevLett.23.1397

Multiplet splitting of core-electron binding energies in transition-metal ions

C. S. Fadley^*, D. A. Shirley, A. J. Freeman, P. S. Bagus, J. V. Mallow

^*Corresponding author for this work

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion.

Original language	English (US)
Pages (from-to)	1397-1401
Number of pages	5
Journal	Physical review letters
Volume	23
Issue number	24
DOIs	https://doi.org/10.1103/PhysRevLett.23.1397
State	Published - 1969

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Physics and Astronomy(all)

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title = "Multiplet splitting of core-electron binding energies in transition-metal ions",

abstract = "X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion.",

author = "Fadley, {C. S.} and Shirley, {D. A.} and Freeman, {A. J.} and Bagus, {P. S.} and Mallow, {J. V.}",

year = "1969",

doi = "10.1103/PhysRevLett.23.1397",

language = "English (US)",

volume = "23",

pages = "1397--1401",

journal = "Physical Review Letters",

issn = "0031-9007",

publisher = "American Physical Society",

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T1 - Multiplet splitting of core-electron binding energies in transition-metal ions

AU - Fadley, C. S.

AU - Shirley, D. A.

AU - Freeman, A. J.

AU - Bagus, P. S.

AU - Mallow, J. V.

PY - 1969

Y1 - 1969

N2 - X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion.

AB - X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion.

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DO - 10.1103/PhysRevLett.23.1397

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JO - Physical Review Letters

JF - Physical Review Letters

IS - 24

ER -

Multiplet splitting of core-electron binding energies in transition-metal ions

Abstract

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