Abstract
X-ray photoelectron spectra indicate core-electron binding-energy splittings of 6 eV for the 3s levels in MnF2, MnO, and FeF3, and less pronounced effects on the 3s levels in MnO2 and Fe metal. These splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The 3p multiplet splittings are shown to behave in a quantitatively different fashion.
Original language | English (US) |
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Pages (from-to) | 1397-1401 |
Number of pages | 5 |
Journal | Physical review letters |
Volume | 23 |
Issue number | 24 |
DOIs | |
State | Published - 1969 |
ASJC Scopus subject areas
- Physics and Astronomy(all)