TY - JOUR
T1 - Nanoscale Cellular Structures at Phase Boundaries of Ni-Cr-Al-Ti and Ni-Cr-Mo-Al-Ti Superalloys
AU - Wang, Cong
AU - Dunand, David C
PY - 2015/6/1
Y1 - 2015/6/1
N2 - The microstructural evolution of Ni-20 pct Cr wires was studied during pack cementation where Al and Ti, with and without prior cementation with Mo, are deposited to the surface of the Ni-Cr wires and subsequently homogenized in their volumes. Mo deposition promotes the formation of Kirkendall pores and subsequent co-deposition of Al and Ti creates a triple-layered diffusional coating on the wire surface. Subsequent homogenization drives the alloying element to distribute evenly in the wires which upon further heat treatment exhibit the γ + γ′ superalloy structure. Unexpectedly, formation of cellular structures is observed at some of the boundaries between primary γ′ grains and γ matrix grains. Based on additional features (i.e., ordered but not perfectly periodic structure, confinement at γ + γ′ phase boundaries as a cellular film with ~100 nm width, as well as lack of topologically close-packed phases), and considering that similar, but much larger, microstructures were reported in commercial superalloys, it is concluded that the present cellular structure solidified as a thin film, composed of eutectic γ + γ′ and from which the γ′ phase was subsequently etched, which was created by incipient melting of a region near the phase boundary with high solute segregation.
AB - The microstructural evolution of Ni-20 pct Cr wires was studied during pack cementation where Al and Ti, with and without prior cementation with Mo, are deposited to the surface of the Ni-Cr wires and subsequently homogenized in their volumes. Mo deposition promotes the formation of Kirkendall pores and subsequent co-deposition of Al and Ti creates a triple-layered diffusional coating on the wire surface. Subsequent homogenization drives the alloying element to distribute evenly in the wires which upon further heat treatment exhibit the γ + γ′ superalloy structure. Unexpectedly, formation of cellular structures is observed at some of the boundaries between primary γ′ grains and γ matrix grains. Based on additional features (i.e., ordered but not perfectly periodic structure, confinement at γ + γ′ phase boundaries as a cellular film with ~100 nm width, as well as lack of topologically close-packed phases), and considering that similar, but much larger, microstructures were reported in commercial superalloys, it is concluded that the present cellular structure solidified as a thin film, composed of eutectic γ + γ′ and from which the γ′ phase was subsequently etched, which was created by incipient melting of a region near the phase boundary with high solute segregation.
UR - http://www.scopus.com/inward/record.url?scp=84940005619&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84940005619&partnerID=8YFLogxK
U2 - 10.1007/s11661-015-2831-6
DO - 10.1007/s11661-015-2831-6
M3 - Article
AN - SCOPUS:84940005619
VL - 46
SP - 2680
EP - 2687
JO - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
JF - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
SN - 1073-5623
IS - 6
ER -