NaPdPS4 and RbPdPS4: Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}

Servane Coste; Jason Hanko; Martine Bujoli-Doeuff; Guy Louarn; Michel Evain; Raymond Brec; Bruno Alonso; Stéphane Jobic; Mercouri G. Kanatzidis

doi:10.1016/S0022-4596(03)00138-5

NaPdPS₄ and RbPdPS₄: Systems with infinite straight 1/∞ [PdPS₄]^- chains soluble in polar solvents and the structure of cubic RbPdPS₄{Rb_0.33P_0.4S _2.23O_x}

Servane Coste, Jason Hanko, Martine Bujoli-Doeuff, Guy Louarn, Michel Evain, Raymond Brec, Bruno Alonso, Stéphane Jobic, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS₄, RbPdPS₄, and RbPdPS₄{Rb _0.33P_0.4S_2.23O_x} are described. NaPdPS₄, RbPdPS₄, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS₄{Rb_0.33P_0.4S_2.23O _x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS₄]^- chains made of alternating square planar Pd²⁺ cations and tetrahedral [PS ₄]^3- anions. RbPdPS₄{Rb_0.33P _0.4S_2.23O_x} contains co-crystallized highly disordered molecular species encapsulated within [Rb₈] cubic cavities. Spectroscopic solid state ³¹P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S _n^2- (n=3 or 4) anions and possibly cationic [P ₄S₆O]⁶⁺ fragments. NaPdPS₄ and RbPdPS₄ exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

Original language	English (US)
Pages (from-to)	133-145
Number of pages	13
Journal	Journal of Solid State Chemistry
Volume	175
Issue number	2
DOIs	https://doi.org/10.1016/S0022-4596(03)00138-5
State	Published - Nov 2003

Keywords

Chain-like materials
Complex fluid
Exfoliation
IR and Raman spectroscopies
P NMR
Palladium
Thiophosphates
X-ray diffraction

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-4596(03)00138-5

Cite this

Coste, S., Hanko, J., Bujoli-Doeuff, M., Louarn, G., Evain, M., Brec, R., Alonso, B., Jobic, S., & Kanatzidis, M. G. (2003). NaPdPS₄ and RbPdPS₄: Systems with infinite straight 1/∞ [PdPS₄]^- chains soluble in polar solvents and the structure of cubic RbPdPS₄{Rb_0.33P_0.4S _2.23O_x}. Journal of Solid State Chemistry, 175(2), 133-145. https://doi.org/10.1016/S0022-4596(03)00138-5

@article{022d3727068a43a1937fa020216dba67,

title = "NaPdPS4 and RbPdPS4: Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}",

abstract = "The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8){\AA}, c=12.2308(14){\AA} and a=8.2954(3){\AA}, c=12.2284(4){\AA} respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2){\AA}. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.",

keywords = "Chain-like materials, Complex fluid, Exfoliation, IR and Raman spectroscopies, P NMR, Palladium, Thiophosphates, X-ray diffraction",

author = "Servane Coste and Jason Hanko and Martine Bujoli-Doeuff and Guy Louarn and Michel Evain and Raymond Brec and Bruno Alonso and St{\'e}phane Jobic and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Financial support from the National Science Foundation (DMR-0127644) is gratefully acknowledged. ",

year = "2003",

month = nov,

doi = "10.1016/S0022-4596(03)00138-5",

language = "English (US)",

volume = "175",

pages = "133--145",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

}

Coste, S, Hanko, J, Bujoli-Doeuff, M, Louarn, G, Evain, M, Brec, R, Alonso, B, Jobic, S & Kanatzidis, MG 2003, 'NaPdPS₄ and RbPdPS₄: Systems with infinite straight 1/∞ [PdPS₄]^- chains soluble in polar solvents and the structure of cubic RbPdPS₄{Rb_0.33P_0.4S _2.23O_x}', Journal of Solid State Chemistry, vol. 175, no. 2, pp. 133-145. https://doi.org/10.1016/S0022-4596(03)00138-5

TY - JOUR

T1 - NaPdPS4 and RbPdPS4

T2 - Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}

AU - Coste, Servane

AU - Hanko, Jason

AU - Bujoli-Doeuff, Martine

AU - Louarn, Guy

AU - Evain, Michel

AU - Brec, Raymond

AU - Alonso, Bruno

AU - Jobic, Stéphane

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: Financial support from the National Science Foundation (DMR-0127644) is gratefully acknowledged.

PY - 2003/11

Y1 - 2003/11

N2 - The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

AB - The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

KW - Chain-like materials

KW - Complex fluid

KW - Exfoliation

KW - IR and Raman spectroscopies

KW - P NMR

KW - Palladium

KW - Thiophosphates

KW - X-ray diffraction

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UR - http://www.scopus.com/inward/citedby.url?scp=0141957278&partnerID=8YFLogxK

U2 - 10.1016/S0022-4596(03)00138-5

DO - 10.1016/S0022-4596(03)00138-5

M3 - Article

AN - SCOPUS:0141957278

SN - 0022-4596

VL - 175

SP - 133

EP - 145

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -