Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells

Weijun Ke; Cong Chen; Ioannis Spanopoulos; Lingling Mao; Ido Hadar; Xiaotong Li; Justin M. Hoffman; Zhaoning Song; Yanfa Yan; Mercouri G. Kanatzidis

doi:10.1021/jacs.0c06288

Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells

Weijun Ke, Cong Chen, Ioannis Spanopoulos, Lingling Mao, Ido Hadar, Xiaotong Li, Justin M. Hoffman, Zhaoning Song, Yanfa Yan, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

The advent of the two-dimensional (2D) family of halide perovskites and their demonstration in 2D/three-dimensional (3D) hierarchical film structures broke new ground toward high device performance and good stability. The 2D Dion-Jacobson (DJ) phase halide perovskites are especially attractive in solar cells because of their superior charge transport properties. Here, we report on 2D DJ phase perovskites using a 3-(aminomethyl)piperidinium (3AMP) organic spacer for the fabrication of mixed Pb/Sn-based perovskites, exhibiting a narrow bandgap of 1.27 eV and a long carrier lifetime of 657.7 ns. Consequently, solar cells employing mixed 2D DJ 3AMP-based and 3D MA0.5FA0.5Pb0.5Sn0.5I3 (MA = methylammonium, FA = formamidinium) perovskite composites as light absorbers achieve enhanced efficiency and stability, giving a power conversion efficiency of 20.09% with a high open-circuit voltage of 0.88 V, a fill factor of 79.74%, and a short-circuit current density of 28.63 mA cm-2. The results provide an effective strategy to improve the performance of single-junction narrow-bandgap solar cells and, potentially, to give a highly efficient alternative to bottom solar cells in tandem devices.

Original language	English (US)
Pages (from-to)	15049-15057
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	142
Issue number	35
DOIs	https://doi.org/10.1021/jacs.0c06288
State	Published - Sep 2 2020

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.0c06288

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@article{98219d30aabf4c4ba62a6968ebd3b858,

title = "Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells",

abstract = "The advent of the two-dimensional (2D) family of halide perovskites and their demonstration in 2D/three-dimensional (3D) hierarchical film structures broke new ground toward high device performance and good stability. The 2D Dion-Jacobson (DJ) phase halide perovskites are especially attractive in solar cells because of their superior charge transport properties. Here, we report on 2D DJ phase perovskites using a 3-(aminomethyl)piperidinium (3AMP) organic spacer for the fabrication of mixed Pb/Sn-based perovskites, exhibiting a narrow bandgap of 1.27 eV and a long carrier lifetime of 657.7 ns. Consequently, solar cells employing mixed 2D DJ 3AMP-based and 3D MA0.5FA0.5Pb0.5Sn0.5I3 (MA = methylammonium, FA = formamidinium) perovskite composites as light absorbers achieve enhanced efficiency and stability, giving a power conversion efficiency of 20.09% with a high open-circuit voltage of 0.88 V, a fill factor of 79.74%, and a short-circuit current density of 28.63 mA cm-2. The results provide an effective strategy to improve the performance of single-junction narrow-bandgap solar cells and, potentially, to give a highly efficient alternative to bottom solar cells in tandem devices.",

author = "Weijun Ke and Cong Chen and Ioannis Spanopoulos and Lingling Mao and Ido Hadar and Xiaotong Li and Hoffman, {Justin M.} and Zhaoning Song and Yanfa Yan and Kanatzidis, {Mercouri G.}",

note = "Funding Information: This work was supported in part by the ONR (N00014-20-1-2725). This work made use of the EPIC and SPID facility (NUANCE Center-Northwestern University), which have received support from the MRSEC program (NSF DMR-1720139) at the Materials Research Center, and the Nanoscale Science and Engineering Center (EEC-0118025/003), both programs of the National Science Foundation; the State of Illinois; and Northwestern University. Publisher Copyright: Copyright {\textcopyright} 2020 American Chemical Society.",

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month = sep,

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doi = "10.1021/jacs.0c06288",

language = "English (US)",

volume = "142",

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T1 - Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells

AU - Ke, Weijun

AU - Chen, Cong

AU - Spanopoulos, Ioannis

AU - Mao, Lingling

AU - Hadar, Ido

AU - Li, Xiaotong

AU - Hoffman, Justin M.

AU - Song, Zhaoning

AU - Yan, Yanfa

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: This work was supported in part by the ONR (N00014-20-1-2725). This work made use of the EPIC and SPID facility (NUANCE Center-Northwestern University), which have received support from the MRSEC program (NSF DMR-1720139) at the Materials Research Center, and the Nanoscale Science and Engineering Center (EEC-0118025/003), both programs of the National Science Foundation; the State of Illinois; and Northwestern University. Publisher Copyright: Copyright © 2020 American Chemical Society.

PY - 2020/9/2

Y1 - 2020/9/2

N2 - The advent of the two-dimensional (2D) family of halide perovskites and their demonstration in 2D/three-dimensional (3D) hierarchical film structures broke new ground toward high device performance and good stability. The 2D Dion-Jacobson (DJ) phase halide perovskites are especially attractive in solar cells because of their superior charge transport properties. Here, we report on 2D DJ phase perovskites using a 3-(aminomethyl)piperidinium (3AMP) organic spacer for the fabrication of mixed Pb/Sn-based perovskites, exhibiting a narrow bandgap of 1.27 eV and a long carrier lifetime of 657.7 ns. Consequently, solar cells employing mixed 2D DJ 3AMP-based and 3D MA0.5FA0.5Pb0.5Sn0.5I3 (MA = methylammonium, FA = formamidinium) perovskite composites as light absorbers achieve enhanced efficiency and stability, giving a power conversion efficiency of 20.09% with a high open-circuit voltage of 0.88 V, a fill factor of 79.74%, and a short-circuit current density of 28.63 mA cm-2. The results provide an effective strategy to improve the performance of single-junction narrow-bandgap solar cells and, potentially, to give a highly efficient alternative to bottom solar cells in tandem devices.

AB - The advent of the two-dimensional (2D) family of halide perovskites and their demonstration in 2D/three-dimensional (3D) hierarchical film structures broke new ground toward high device performance and good stability. The 2D Dion-Jacobson (DJ) phase halide perovskites are especially attractive in solar cells because of their superior charge transport properties. Here, we report on 2D DJ phase perovskites using a 3-(aminomethyl)piperidinium (3AMP) organic spacer for the fabrication of mixed Pb/Sn-based perovskites, exhibiting a narrow bandgap of 1.27 eV and a long carrier lifetime of 657.7 ns. Consequently, solar cells employing mixed 2D DJ 3AMP-based and 3D MA0.5FA0.5Pb0.5Sn0.5I3 (MA = methylammonium, FA = formamidinium) perovskite composites as light absorbers achieve enhanced efficiency and stability, giving a power conversion efficiency of 20.09% with a high open-circuit voltage of 0.88 V, a fill factor of 79.74%, and a short-circuit current density of 28.63 mA cm-2. The results provide an effective strategy to improve the performance of single-junction narrow-bandgap solar cells and, potentially, to give a highly efficient alternative to bottom solar cells in tandem devices.

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SN - 0002-7863

VL - 142

SP - 15049

EP - 15057

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 35

ER -

Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells

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CCDC 2025356: Experimental Crystal Structure Determination

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Narrow-bandgap mixed lead/tin-based 2D Dion-Jacobson perovskites boost the performance of solar cells

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CCDC 2025356: Experimental Crystal Structure Determination

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