Na3VOS3

Fu Qiang Huang; James A. Ibers

doi:10.1107/S1600536803028939

Na₃VOS₃

Fu Qiang Huang, James A. Ibers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li₂O/Na ₂S flux at 723 K. The structure comprises isolated tetrahedral VOS₃^3- anions separated by Na⁺ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) Å, and V-S = 2.1746 (4) and 2.1971 (6) Å. Each Na⁺ cation is coordinated in a distorted octahedron by one O and five S atoms.

Original language	English (US)
Pages (from-to)	i6-i7
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	1
DOIs	https://doi.org/10.1107/S1600536803028939
State	Published - Jan 2004
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536803028939

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title = "Na3VOS3",

abstract = "The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li2O/Na 2S flux at 723 K. The structure comprises isolated tetrahedral VOS33- anions separated by Na+ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) {\AA}, and V-S = 2.1746 (4) and 2.1971 (6) {\AA}. Each Na+ cation is coordinated in a distorted octahedron by one O and five S atoms.",

author = "Huang, {Fu Qiang} and Ibers, {James A.}",

year = "2004",

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doi = "10.1107/S1600536803028939",

language = "English (US)",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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AU - Ibers, James A.

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N2 - The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li2O/Na 2S flux at 723 K. The structure comprises isolated tetrahedral VOS33- anions separated by Na+ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) Å, and V-S = 2.1746 (4) and 2.1971 (6) Å. Each Na+ cation is coordinated in a distorted octahedron by one O and five S atoms.

AB - The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li2O/Na 2S flux at 723 K. The structure comprises isolated tetrahedral VOS33- anions separated by Na+ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) Å, and V-S = 2.1746 (4) and 2.1971 (6) Å. Each Na+ cation is coordinated in a distorted octahedron by one O and five S atoms.

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ER -

Na₃VOS₃

Abstract

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