The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li2O/Na 2S flux at 723 K. The structure comprises isolated tetrahedral VOS33- anions separated by Na+ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) Å, and V-S = 2.1746 (4) and 2.1971 (6) Å. Each Na+ cation is coordinated in a distorted octahedron by one O and five S atoms.
|Original language||English (US)|
|Journal||Acta Crystallographica Section E: Structure Reports Online|
|State||Published - Jan 1 2004|
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics