Na3VOS3

Fu Qiang Huang, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The title compound, trisodium vanadium oxide trisulfide, has been synthesized by the reaction of the elements in an Li2O/Na 2S flux at 723 K. The structure comprises isolated tetrahedral VOS33- anions separated by Na+ cations. The anion has symmetry m. Bond distances include V-O = 1.673 (2) Å, and V-S = 2.1746 (4) and 2.1971 (6) Å. Each Na+ cation is coordinated in a distorted octahedron by one O and five S atoms.

Original languageEnglish (US)
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number1
DOIs
StatePublished - Jan 1 2004

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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