New complex compounds based on [Re6Te8(CN) 6]4- cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites

K. A. Brylev*, N. G. Naumov, V. E. Fedorov, J. A. Ibers

*Corresponding author for this work

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN) 6]·4H2O (1), [Cu(dien)2] 2[Re6Te8(CN)6]·4H 2O (2), and [Co(dien)2]3[Re6Te 8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of COCl2·6H 2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.

Original languageEnglish (US)
Pages (from-to)S130-S136
JournalJournal of Structural Chemistry
Volume46
Issue number1 SUPPL.
DOIs
StatePublished - Jan 2006

Keywords

  • Cyanide
  • Rhenium cluster
  • Transition-metal amine
  • X-ray structure

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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