New complex compounds based on [Re6Te8(CN) 6]4- cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites

K. A. Brylev; N. G. Naumov; V. E. Fedorov; J. A. Ibers

doi:10.1007/s10947-006-0163-5

New complex compounds based on [Re₆Te₈(CN) ₆]^4- cluster anions and [M(dien)₂]²⁺ (M = Co²⁺ and Cu²⁺) cations: Adjustment of the crystal structure by the blocking of coordination sites

K. A. Brylev^*, N. G. Naumov, V. E. Fedorov, J. A. Ibers

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)₂]₂[Re₆Te₈(CN) ₆]·4H₂O (1), [Cu(dien)₂] ₂[Re₆Te₈(CN)₆]·4H ₂O (2), and [Co(dien)₂]₃[Re₆Te ₈(CN)₆]Br₂·H₂O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs₄[Re₆Te₈(CN)₆]·2H ₂O into a glycerol solution of COCl₂·6H ₂O (for 1 and 3) or CuCl₂·2H₂O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.

Original language	English (US)
Pages (from-to)	S130-S136
Journal	Journal of Structural Chemistry
Volume	46
Issue number	1 SUPPL.
DOIs	https://doi.org/10.1007/s10947-006-0163-5
State	Published - Jan 2006

Keywords

Cyanide
Rhenium cluster
Transition-metal amine
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1007/s10947-006-0163-5

Cite this

@article{f38624321a4f4e5aa1a036eab5679b55,

title = "New complex compounds based on [Re6Te8(CN) 6]4- cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations: Adjustment of the crystal structure by the blocking of coordination sites",

abstract = "Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN) 6]·4H2O (1), [Cu(dien)2] 2[Re6Te8(CN)6]·4H 2O (2), and [Co(dien)2]3[Re6Te 8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of COCl2·6H 2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.",

keywords = "Cyanide, Rhenium cluster, Transition-metal amine, X-ray structure",

author = "Brylev, {K. A.} and Naumov, {N. G.} and Fedorov, {V. E.} and Ibers, {J. A.}",

note = "Funding Information: This research was supported by the U. S. National Science Foundation (grant No. CHE-9819385), the Russian Foundation for Basic Research (grant No. 02-03-32264), and the Foundation of the President of the Russian Federation (Federal Program for the Support of Leading Scientific Schools, Project No. NSh-1042.2003.3).",

year = "2006",

month = jan,

doi = "10.1007/s10947-006-0163-5",

language = "English (US)",

volume = "46",

pages = "S130--S136",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "1 SUPPL.",

}

New complex compounds based on [Re₆Te₈(CN) ₆]^4- cluster anions and [M(dien)₂]²⁺ (M = Co²⁺ and Cu²⁺) cations: Adjustment of the crystal structure by the blocking of coordination sites. / Brylev, K. A.; Naumov, N. G.; Fedorov, V. E. et al.
In: Journal of Structural Chemistry, Vol. 46, No. 1 SUPPL., 01.2006, p. S130-S136.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - New complex compounds based on [Re6Te8(CN) 6]4- cluster anions and [M(dien)2]2+ (M = Co2+ and Cu2+) cations

T2 - Adjustment of the crystal structure by the blocking of coordination sites

AU - Brylev, K. A.

AU - Naumov, N. G.

AU - Fedorov, V. E.

AU - Ibers, J. A.

N1 - Funding Information: This research was supported by the U. S. National Science Foundation (grant No. CHE-9819385), the Russian Foundation for Basic Research (grant No. 02-03-32264), and the Foundation of the President of the Russian Federation (Federal Program for the Support of Leading Scientific Schools, Project No. NSh-1042.2003.3).

PY - 2006/1

Y1 - 2006/1

N2 - Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN) 6]·4H2O (1), [Cu(dien)2] 2[Re6Te8(CN)6]·4H 2O (2), and [Co(dien)2]3[Re6Te 8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of COCl2·6H 2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.

AB - Three new octahedral ionic rhenium tellurocyanide cluster compounds [Co(dien)2]2[Re6Te8(CN) 6]·4H2O (1), [Cu(dien)2] 2[Re6Te8(CN)6]·4H 2O (2), and [Co(dien)2]3[Re6Te 8(CN)6]Br2·H2O (3) (dien = diethylenetriamine) have been obtained by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of COCl2·6H 2O (for 1 and 3) or CuCl2·2H2O (for 2) in the presence of dien. The compounds have been characterized by single-crystal X-ray diffraction methods and by elemental analyses.

KW - Cyanide

KW - Rhenium cluster

KW - Transition-metal amine

KW - X-ray structure

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