New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine

Konstantin A. Brylev; Yuri V. Mironov; Nikolai G. Naumov; Vladimir E. Fedorov; James A. Ibers

doi:10.1021/ic040046j

New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine

Konstantin A. Brylev, Yuri V. Mironov, Nikolai G. Naumov, Vladimir E. Fedorov, James A. Ibers^*

^*Corresponding author for this work

Chemistry

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Abstract

The compounds [Ni(en)₃]₂[Re₆Te ₈(CN)₆]·10H₂O (1), [Ni(NH ₃)₄(en)]₂[Re₆Te₈(CN) ₆]·2H₂O (2), [Ni(NH₃) ₂(en)₂][{Ni(en)₂}₃{Re ₄Te₄(CN)₁₂}₂]·38H ₂O (3), [Co(NH₃)₂(en)₂] ₂[{Co(en)₂}Re₆Te₈(CN) ₆]Cl₂·H₂O (4), and [{Zn(H ₂O)(en)₂}{Zn(en)₂}Re₆Te ₈(CN)₆]·3H₂O (5) (en = ethylenediamine) have been synthesized and characterized. Compounds 1, 4, and 5 have been synthesized by the diffusion of an aqueous (for 1 and 5) or an ammonia (for 4) solution of Cs₄[Re₆Te₈(CN)₆] ·2H₂O into a glycerol solution of NiCl₂· 6H₂O (for 1), CoCl₂·6H₂O (for 4), or ZnCl₂ (for 5). Compounds 2 and 3 have been synthesized by the reaction of an aqueous solution of Cs₄[Re₆Te ₈(CN)₆]·2H₂O (for 2) or K ₄[Re₄Te₄(CN)₁₂]·5H ₂O (for 3) with an ammonia solution of Ni(en)₂Cl ₂. Compounds 1 and 2 are ionic whereas compounds 4 and 5 are one-dimensional polymers. Compound 3, a two-dimensional polymer, possesses hexagonal shaped channels of approximate diameter 10-12 Å. Because the framework of compound 3 is robust, it is an attractive host for guest molecules of appropriate size and shape. The potential "guest" volume is about 37% of the unit cell volume.

Original language	English (US)
Pages (from-to)	4833-4838
Number of pages	6
Journal	Inorganic chemistry
Volume	43
Issue number	16
DOIs	https://doi.org/10.1021/ic040046j
State	Published - Aug 9 2004

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry

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10.1021/ic040046j

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@article{dd5f050e56de451b9bbf062b4e6c93b7,

title = "New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine",

abstract = "The compounds [Ni(en)3]2[Re6Te 8(CN)6]·10H2O (1), [Ni(NH 3)4(en)]2[Re6Te8(CN) 6]·2H2O (2), [Ni(NH3) 2(en)2][{Ni(en)2}3{Re 4Te4(CN)12}2]·38H 2O (3), [Co(NH3)2(en)2] 2[{Co(en)2}Re6Te8(CN) 6]Cl2·H2O (4), and [{Zn(H 2O)(en)2}{Zn(en)2}Re6Te 8(CN)6]·3H2O (5) (en = ethylenediamine) have been synthesized and characterized. Compounds 1, 4, and 5 have been synthesized by the diffusion of an aqueous (for 1 and 5) or an ammonia (for 4) solution of Cs4[Re6Te8(CN)6] ·2H2O into a glycerol solution of NiCl2· 6H2O (for 1), CoCl2·6H2O (for 4), or ZnCl2 (for 5). Compounds 2 and 3 have been synthesized by the reaction of an aqueous solution of Cs4[Re6Te 8(CN)6]·2H2O (for 2) or K 4[Re4Te4(CN)12]·5H 2O (for 3) with an ammonia solution of Ni(en)2Cl 2. Compounds 1 and 2 are ionic whereas compounds 4 and 5 are one-dimensional polymers. Compound 3, a two-dimensional polymer, possesses hexagonal shaped channels of approximate diameter 10-12 {\AA}. Because the framework of compound 3 is robust, it is an attractive host for guest molecules of appropriate size and shape. The potential {"}guest{"} volume is about 37% of the unit cell volume.",

author = "Brylev, {Konstantin A.} and Mironov, {Yuri V.} and Naumov, {Nikolai G.} and Fedorov, {Vladimir E.} and Ibers, {James A.}",

year = "2004",

month = aug,

day = "9",

doi = "10.1021/ic040046j",

language = "English (US)",

volume = "43",

pages = "4833--4838",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "16",

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TY - JOUR

T1 - New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine

AU - Brylev, Konstantin A.

AU - Mironov, Yuri V.

AU - Naumov, Nikolai G.

AU - Fedorov, Vladimir E.

AU - Ibers, James A.

PY - 2004/8/9

Y1 - 2004/8/9

N2 - The compounds [Ni(en)3]2[Re6Te 8(CN)6]·10H2O (1), [Ni(NH 3)4(en)]2[Re6Te8(CN) 6]·2H2O (2), [Ni(NH3) 2(en)2][{Ni(en)2}3{Re 4Te4(CN)12}2]·38H 2O (3), [Co(NH3)2(en)2] 2[{Co(en)2}Re6Te8(CN) 6]Cl2·H2O (4), and [{Zn(H 2O)(en)2}{Zn(en)2}Re6Te 8(CN)6]·3H2O (5) (en = ethylenediamine) have been synthesized and characterized. Compounds 1, 4, and 5 have been synthesized by the diffusion of an aqueous (for 1 and 5) or an ammonia (for 4) solution of Cs4[Re6Te8(CN)6] ·2H2O into a glycerol solution of NiCl2· 6H2O (for 1), CoCl2·6H2O (for 4), or ZnCl2 (for 5). Compounds 2 and 3 have been synthesized by the reaction of an aqueous solution of Cs4[Re6Te 8(CN)6]·2H2O (for 2) or K 4[Re4Te4(CN)12]·5H 2O (for 3) with an ammonia solution of Ni(en)2Cl 2. Compounds 1 and 2 are ionic whereas compounds 4 and 5 are one-dimensional polymers. Compound 3, a two-dimensional polymer, possesses hexagonal shaped channels of approximate diameter 10-12 Å. Because the framework of compound 3 is robust, it is an attractive host for guest molecules of appropriate size and shape. The potential "guest" volume is about 37% of the unit cell volume.

AB - The compounds [Ni(en)3]2[Re6Te 8(CN)6]·10H2O (1), [Ni(NH 3)4(en)]2[Re6Te8(CN) 6]·2H2O (2), [Ni(NH3) 2(en)2][{Ni(en)2}3{Re 4Te4(CN)12}2]·38H 2O (3), [Co(NH3)2(en)2] 2[{Co(en)2}Re6Te8(CN) 6]Cl2·H2O (4), and [{Zn(H 2O)(en)2}{Zn(en)2}Re6Te 8(CN)6]·3H2O (5) (en = ethylenediamine) have been synthesized and characterized. Compounds 1, 4, and 5 have been synthesized by the diffusion of an aqueous (for 1 and 5) or an ammonia (for 4) solution of Cs4[Re6Te8(CN)6] ·2H2O into a glycerol solution of NiCl2· 6H2O (for 1), CoCl2·6H2O (for 4), or ZnCl2 (for 5). Compounds 2 and 3 have been synthesized by the reaction of an aqueous solution of Cs4[Re6Te 8(CN)6]·2H2O (for 2) or K 4[Re4Te4(CN)12]·5H 2O (for 3) with an ammonia solution of Ni(en)2Cl 2. Compounds 1 and 2 are ionic whereas compounds 4 and 5 are one-dimensional polymers. Compound 3, a two-dimensional polymer, possesses hexagonal shaped channels of approximate diameter 10-12 Å. Because the framework of compound 3 is robust, it is an attractive host for guest molecules of appropriate size and shape. The potential "guest" volume is about 37% of the unit cell volume.

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JF - Inorganic chemistry

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New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine

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CCDC 248356: Experimental Crystal Structure Determination

CCDC 248357: Experimental Crystal Structure Determination

CCDC 248355: Experimental Crystal Structure Determination

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New compounds from tellurocyanide rhenium cluster anions and 3d-transition metal cations coordinated with ethylenediamine

Abstract

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CCDC 248356: Experimental Crystal Structure Determination

CCDC 248357: Experimental Crystal Structure Determination

CCDC 248355: Experimental Crystal Structure Determination

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