New conductive polymeric materials: Cofacial assembly of mixed valent metallomacrocycles

Tobin J. Marks; Karl F. Schoch; Bhagyashree R. Kundalkar

doi:10.1016/0379-6779(80)90023-5

New conductive polymeric materials: Cofacial assembly of mixed valent metallomacrocycles

Tobin J. Marks^*, Karl F. Schoch, Bhagyashree R. Kundalkar

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

This paper reports on an approach to control molecular stacking interactions in low-dimensional mixed valence materials by locking partially oxidized metallomacrocycles together in a cofacial orientation. Iodine doping of the face-to-face linked oligomers [M(Pc)O]_n (M = Si, Ge, Sn; Pc = phthalocyaninato) produces electrically conductive polymers {[M(Pc)O]I_xn with a wide range of x stoichiometries. Resonance Raman spectroscopy indicates that the iodine has oxidized the polymer chain. Polymer structure has been studied by X-ray powder diffraction, and it is possible to estimate interplanar spacings. Halogen doping of the [M(Pc)O]_n materials is accompanied by electrical conductivity increases as large 10⁷ (ohm cm)^-1; the general trend is σ_Si {greater-than or approximate} σ_Ge > σ_Sn. Variable temperature conductivity and magnetic susceptibility data are reported.

Original language	English (US)
Pages (from-to)	337-347
Number of pages	11
Journal	Synthetic Metals
Volume	1
Issue number	3
DOIs	https://doi.org/10.1016/0379-6779(80)90023-5
State	Published - Apr 1980

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/0379-6779(80)90023-5

Cite this

@article{499ac413d7134b75a03a5be07c3b23f4,

title = "New conductive polymeric materials: Cofacial assembly of mixed valent metallomacrocycles",

abstract = "This paper reports on an approach to control molecular stacking interactions in low-dimensional mixed valence materials by locking partially oxidized metallomacrocycles together in a cofacial orientation. Iodine doping of the face-to-face linked oligomers [M(Pc)O]n (M = Si, Ge, Sn; Pc = phthalocyaninato) produces electrically conductive polymers {[M(Pc)O]Ixn with a wide range of x stoichiometries. Resonance Raman spectroscopy indicates that the iodine has oxidized the polymer chain. Polymer structure has been studied by X-ray powder diffraction, and it is possible to estimate interplanar spacings. Halogen doping of the [M(Pc)O]n materials is accompanied by electrical conductivity increases as large 107 (ohm cm)-1; the general trend is σSi {greater-than or approximate} σGe > σSn. Variable temperature conductivity and magnetic susceptibility data are reported.",

author = "Marks, {Tobin J.} and Schoch, {Karl F.} and Kundalkar, {Bhagyashree R.}",

year = "1980",

month = apr,

doi = "10.1016/0379-6779(80)90023-5",

language = "English (US)",

volume = "1",

pages = "337--347",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "3",

}

TY - JOUR

T1 - New conductive polymeric materials

T2 - Cofacial assembly of mixed valent metallomacrocycles

AU - Marks, Tobin J.

AU - Schoch, Karl F.

AU - Kundalkar, Bhagyashree R.

PY - 1980/4

Y1 - 1980/4

N2 - This paper reports on an approach to control molecular stacking interactions in low-dimensional mixed valence materials by locking partially oxidized metallomacrocycles together in a cofacial orientation. Iodine doping of the face-to-face linked oligomers [M(Pc)O]n (M = Si, Ge, Sn; Pc = phthalocyaninato) produces electrically conductive polymers {[M(Pc)O]Ixn with a wide range of x stoichiometries. Resonance Raman spectroscopy indicates that the iodine has oxidized the polymer chain. Polymer structure has been studied by X-ray powder diffraction, and it is possible to estimate interplanar spacings. Halogen doping of the [M(Pc)O]n materials is accompanied by electrical conductivity increases as large 107 (ohm cm)-1; the general trend is σSi {greater-than or approximate} σGe > σSn. Variable temperature conductivity and magnetic susceptibility data are reported.

AB - This paper reports on an approach to control molecular stacking interactions in low-dimensional mixed valence materials by locking partially oxidized metallomacrocycles together in a cofacial orientation. Iodine doping of the face-to-face linked oligomers [M(Pc)O]n (M = Si, Ge, Sn; Pc = phthalocyaninato) produces electrically conductive polymers {[M(Pc)O]Ixn with a wide range of x stoichiometries. Resonance Raman spectroscopy indicates that the iodine has oxidized the polymer chain. Polymer structure has been studied by X-ray powder diffraction, and it is possible to estimate interplanar spacings. Halogen doping of the [M(Pc)O]n materials is accompanied by electrical conductivity increases as large 107 (ohm cm)-1; the general trend is σSi {greater-than or approximate} σGe > σSn. Variable temperature conductivity and magnetic susceptibility data are reported.

UR - http://www.scopus.com/inward/record.url?scp=0018458276&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0018458276&partnerID=8YFLogxK

U2 - 10.1016/0379-6779(80)90023-5

DO - 10.1016/0379-6779(80)90023-5

M3 - Article

AN - SCOPUS:0018458276

SN - 0379-6779

VL - 1

SP - 337

EP - 347

JO - Synthetic Metals

JF - Synthetic Metals

IS - 3

ER -

New conductive polymeric materials: Cofacial assembly of mixed valent metallomacrocycles

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this