New cyclophane hosts: A hexaoxacyclophane

George R. Brown; Surinder S. Chana; J. Fraser Stoddart; Alexandra M Z Slawin; David J. Williams

doi:10.1039/P19890000211

New cyclophane hosts: A hexaoxacyclophane

George R. Brown, Surinder S. Chana, J. Fraser Stoddart, Alexandra M Z Slawin, David J. Williams

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The X-ray crystal structure of the hexaoxacyclophane (1), which can be synthesized from 1,3-bis-(bromomethyl)benzene and bis(4-hydroxyphenyl) ether in one step, reveals that in the solid state the macrocyclic ring forms a large molecular void potentially capable of binding aromatic guest molecules: the X-ray crystal structure of the 1:1 molecular complex formed between (1) and benzene exposes intermolecular and intercomplex aromatic ring interactions of an edge-to-face type.

Original language	English (US)
Pages (from-to)	211-212
Number of pages	2
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	1
DOIs	https://doi.org/10.1039/P19890000211
State	Published - 1989

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Chemistry(all)

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AU - Chana, Surinder S.

AU - Stoddart, J. Fraser

AU - Slawin, Alexandra M Z

AU - Williams, David J.

PY - 1989

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AB - The X-ray crystal structure of the hexaoxacyclophane (1), which can be synthesized from 1,3-bis-(bromomethyl)benzene and bis(4-hydroxyphenyl) ether in one step, reveals that in the solid state the macrocyclic ring forms a large molecular void potentially capable of binding aromatic guest molecules: the X-ray crystal structure of the 1:1 molecular complex formed between (1) and benzene exposes intermolecular and intercomplex aromatic ring interactions of an edge-to-face type.

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New cyclophane hosts: A hexaoxacyclophane

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