Ni(ii) complex on a bispyridine-based porous organic polymer as a heterogeneous catalyst for ethylene oligomerization

Min Jeong Kim, Sol Ahn, Jigyoung Yi, Joseph T. Hupp, Justin M. Notestein, Omar K. Farha, Suk Joong Lee*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

A Ni(ii) catalyst incorporated into a new porous organic polymer, Ni(ii)-POP-1, is prepared via a click reaction followed by metalation with NiCl2. It shows good catalytic activity for liquid-phase ethylene dimerization in the presence of Et2AlCl as a co-catalyst, generating 1-butene.

Original languageEnglish (US)
Pages (from-to)4351-4354
Number of pages4
JournalCatalysis Science and Technology
Volume7
Issue number19
DOIs
StatePublished - 2017

Funding

M. J. Kim, J. Yi, and S. J. Lee acknowledge financial support from the Research Foundation Program (NRF-2016R1D1A1A09918637) and Key Research Institute Program (NRF20100020209) through the National Research Foundation of Korea (NRF). S. Ahn, J. T. Hupp, J. M. Notestein, and O. K. Farha acknowledge financial support from the Inorganometallic Catalyst Design Center, an EFRC funded by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (DESC0012702). Metal analysis was performed at the Northwestern University Quantitative Bio-element Imaging Center.

ASJC Scopus subject areas

  • Catalysis

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