Abstract
A method that enables the determination of quadratic response molecular properties of heterogeneously solvated molecules is presented. The method describes the situation where a solvated molecule is located on a metallic surface. It is demonstrated that the two-photon matrix elements and the frequency-dependent hyperpolarizabilities for a heterogeneously solvated CO molecule depend on the distance to the metal surface and the dielectric constant of the solvent.
Original language | English (US) |
---|---|
Pages (from-to) | 8185-8192 |
Number of pages | 8 |
Journal | Journal of Chemical Physics |
Volume | 115 |
Issue number | 17 |
DOIs | |
State | Published - Nov 1 2001 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry